2007
DOI: 10.1016/j.polymer.2007.09.009
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Porous interpenetrating network hybrids synthesized within high internal phase emulsions

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Cited by 54 publications
(38 citation statements)
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“…[ 43 a] This was also observed when other siloxanes (tetraethylorthosilicate (TEOS)) were used. [ 44 ] It was suggested that DVB was a much more effi cient crosslinker than VSQ, based on an increase in tan δ value from stressstrain curves of a material with no DVB and 40 mol% VSQ compared to a material with 16 mol% DVB and 38 mol% VSQ with respect to the monomer content. [ 43 c] A POSS was also copolymerised with EHA and DVB and was observed at 9 mol% with respect to the monomer content to result in a collapsed foam with increased density in comparison to lower loadings of silsesquioxane.…”
Section: Hybrid Organic-inorganic Emulsion Templated Porous Polymersmentioning
confidence: 99%
“…[ 43 a] This was also observed when other siloxanes (tetraethylorthosilicate (TEOS)) were used. [ 44 ] It was suggested that DVB was a much more effi cient crosslinker than VSQ, based on an increase in tan δ value from stressstrain curves of a material with no DVB and 40 mol% VSQ compared to a material with 16 mol% DVB and 38 mol% VSQ with respect to the monomer content. [ 43 c] A POSS was also copolymerised with EHA and DVB and was observed at 9 mol% with respect to the monomer content to result in a collapsed foam with increased density in comparison to lower loadings of silsesquioxane.…”
Section: Hybrid Organic-inorganic Emulsion Templated Porous Polymersmentioning
confidence: 99%
“…The class II is based on materials with covalent and ionic-covalent bonds [5]. Both hybrid class I and class II have several forms of synthesis, as for instance, the sol-gel process [6][7][8] and polymerization of metal-containing monomers (MCM) [9][10][11][12].…”
Section: Introductionmentioning
confidence: 99%
“…High internal phase emulsions (HIPEs) are one of the innovative synthesis methods currently being used. Normatov et.al [1] has reported that polyHIPEs are a well-established class of porous and permeable materials from the polymerization of monomers and cross-linking of co-monomers in the continuous phase of HIPE. Cameron [2] has reported that the most widely used polyHIPEs are synthesized from styrene and divinylbenzene (DVB) as the organic phase of the emulsion.…”
Section: Introductionmentioning
confidence: 99%
“…They are also compatible and effective biomaterials that are used in many industries. In this research, a biopolymer (BP) is a copolymer of β- [1,4]-linked-2-acetamido-2-deoxy-D-glucopyranose and 2-amino-2-deoxy-D-glucopyranose, which also contains polyamines. Primary amines in the structure have the ability to react with CO 2 .…”
Section: Introductionmentioning
confidence: 99%