KH550 modified halloysite nanotubes (m-HNTs) were hybridized with sulfoxide chloride acylated graphene oxide (m-GO) to prepare hybrid nanoparticles (HNTs-d-GO). The microstructure and morphology analysis of HNTs-d-GO hybrid nanoparticles showed that the ordered lamellar structure of GO after acyl chlorination was stripped, and the organic groups on the surface of the lamellar increased. HNTs-d-GO hybrid nanoparticles were formed through the amidation of m-HNTs and m-GO. Then HNTs-d-GO hybrid nanoparticles were incorporated in galic acid epoxy resin to improve the thermal and mechanical properties. HNTs-d-GO/galic acid epoxy resin (HNTs-d-GO/GAER) bio-based nanocomposites were prepared with methyl tetrahydrophthalic anhydride as curing agent. The galic acid epoxy composites with the addition of HNTs-d-GO exhibited significant enhancements of impact strength, tensile strength, storage modulus, and glass transition temperature. The initial thermal decomposition temperature (T 5% ) decreased, and the mass retention at 800 C increased, thermal stability of HNTs-d-GO/GAER composites were enhanced. At an optimum concentration of 0.75 wt% HNTs-d-GO, a simultaneous increase in strength and toughness was observed in comparison to the unfilled cured resin, the impact strength is 2.87 kJ/m 2 , which is 30.4% higher than pure GAER, and the tensile strength is 42.62 MPa, which is 29.2% higher than pure GAER. Compared with pure gallic acid epoxy resin, the content of HNTs-d-GO is 0.25 wt%, T g increased by 28.9 C.