“…A positive sign of superexchange interactions in ab-planes and negative ones between them are caused by specific 2 z d -orbital ordering of the Mn 3+ ions [1]. A substitution of lanthanum by divalent alkaline [4] leads to a concentration transition to a ferromagnetic state with increasing dopant content. The ferromagnetic behavior of the doped manganates is traditionally explained in terms of the double exchange mechanism [5].…”
“…A positive sign of superexchange interactions in ab-planes and negative ones between them are caused by specific 2 z d -orbital ordering of the Mn 3+ ions [1]. A substitution of lanthanum by divalent alkaline [4] leads to a concentration transition to a ferromagnetic state with increasing dopant content. The ferromagnetic behavior of the doped manganates is traditionally explained in terms of the double exchange mechanism [5].…”
“…[6][7][8][9][10][11][12][13][14] La 1−x B x MnO 3 (B ¼ Mn, Ca) perovskite magnates are well known to show MITs with ferromagnetic-paramagnetic transition. 15 Perovskite materials are also found to be suitable for solid oxide fuel cells. 16,17 ABO 3 is considered as an ideal perovskite material, where A is a monovalent otherwise divalent cation situated on the edges of the crystal, and B is a tetravalent or pentavalent transition metal.…”
Here, we have employed the density functional theory on TlBO3 (B = Cr, Mn) to study the structural, mechanical, electronic, optical, and thermal properties for the first time. Spin polarization causes a metallic-to-semiconducting transition.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.