Potential changes during in situ formation of carriers for cationic surfactant ion-selective electrodes by conditioning

Faozia, Hanifa; Itadani, Naoko; Nomura, Masakazu; Suzuki, Kimihito; Yasui, Takashi; Takada, Keisuke; Yuchi, Akio

doi:10.1016/j.jelechem.2013.03.002

Cited by 7 publications

(5 citation statements)

References 18 publications

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“…This improvement can be interpreted as described below. If no ionic sites are added in the membrane, coextraction of the analyte ion and its counter-ion into the organic phase occurs according to the following reaction [26]:…”

Section: Membranes With Lipophilic Anions As Additivesmentioning

confidence: 99%

Nanomolar Detection of Alkyl Dimethyl Hydroxyethyl Ammonium Surfactant by a Lipophile-doped Solid Contact Electrode

Shawish¹,

Gaber²,

Khedr³

et al. 2014

J Environ Anal Chem

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Section: Membranes With Lipophilic Anions As Additivesmentioning

confidence: 99%

Nanomolar Detection of Alkyl Dimethyl Hydroxyethyl Ammonium Surfactant by a Lipophile-doped Solid Contact Electrode

Shawish¹,

Gaber²,

Khedr³

et al. 2014

J Environ Anal Chem

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“…[21] Thus, several potentiometric ion selective sensors have introduced for the determination of cationic surfactant determination up to now. [4,[22][23][24][25][26][27][28] Many surfactant sensors typically consist of a liquid membrane-type sensor, including an ionophore, high molecular weight PVC, and a plasticizer. [29,30] The ionophore serves as the sensing material and is generally responsible for selective interaction with the surfactant counter-ion and for the formation of the ion-pair.…”

Section: Introductionmentioning

confidence: 99%

“…At this point, because of their remarkable properties, such as high selectivity, broad linear operational range, low limit of detection, high accuracy and precision, short analysis time, simple design, low price, no harm to the measured specimen, no pre‐processing stages, and determination even in colored and sedimentary solutions, potentiometric ion‐selective electrodes/sensors appear as an alternative method to most of the above‐mentioned detection methods for cationic surfactant determination [21] . Thus, several potentiometric ion selective sensors have introduced for the determination of cationic surfactant determination up to now [4,22–28] …”

Section: Introductionmentioning

confidence: 99%

A PVC‐Membrane Cationic Surfactant Sensitive Potentiometric Sensor: Potentiometric Determination of Dodecyltrimethyl Ammonium Ion

Yalcin,

Coldur,

Caglar

et al. 2023

ChemistrySelect

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A potentiometric poly (vinyl chloride) (PVC) membrane cationic surfactant‐selective sensor based on a dodecyltrimethylammonium‐phosphotungstate ion pair as an electroactive material was suggested for the determination of dodecyltrimethylammonium bromide. Membrane optimization studies revealed that the PVC membrane in the composition of 0.5 % dodecyltrimethylammonium‐phosphotungstate ion pair, 69.5 % o‐nitrophenyloctylether and 30.0 % PVC displayed the best potentiometric performance properties. The sensor exhibited a linear response to dodecyltrimethylammonium ions in the concentration range of 1.0×10−6–1.0×10−2 mol L−1 with a detection limit and sensitivity of 5.0×10−7 mol L−1 and 56.6 mV/decade, respectively. The response of the sensor to dodecyltrimethylammonium cation was quite stable, sensitive, selective and rapid (<10 s). The life span of the sensor was found to be about 3 months. The analytical applications of the sensor were successfully carried out with the developed sensor as an indicator electrode for the determination of the end‐point of dodecyltrimethylammonium ions titration and dodecyltrimethylammonium contents of synthetic water samples.

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“…Thus, TFPB is stable under acidic conditions [19]. It has been used as an anion phasetransfer catalyst in Friedel-Craft alkylation or diazo coupling reactions [21], and as an ion exchanger in ion-selective electrodes (ISEs) [22][23][24]. As an anionic lipophilic additive for potentiometer sensors, appropriate TFPB content is important for cation sensing to have better sensitivity and a shorter response time [25].…”

Section: Introductionmentioning

confidence: 99%

Quantification of Pharmaceutical Bitterness Using a Membrane Electrode Based on a Hydrophobic Tetrakis [3,5-Bis (trifluoromethyl) phenyl] Borate

Shiino

Tahara

et al. 2021

Chemosensors

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Technologies for quantifying bitterness are essential for classifying medicines. As previously reported, taste sensors with lipid polymer membranes can respond to bitter hydrochloride substances in pharmaceuticals. However, the acid hydrolysis reaction between the lipid phosphoric acid di-n-decyl ester (PADE) and the plasticizer tributyl o-acetylcitrate (TDAB) led to a deterioration in sensor responses during storage. Given the cost of transportation and preservation for commercialization, membrane components that maintain physical and chemical stability during long-term storage are needed. Here we present a membrane electrode based on hydrophobic tetrakis [3,5-bis (trifluoromethyl) phenyl] borate (TFPB) and a plasticizer 2-nitrophenyl octyl ether (NPOE) for the quantification of pharmaceutical bitterness; they maintain a stable response before and after accelerated deterioration, as well as high selectivity and sensitivity. It is a first attempt to use a completely dissociative substance to replace non-completely dissociative lipids. Our work offsets the long-term stability issue of a bitterness sensor with a negatively charged hydrophobic membrane. Meanwhile, we provide the opportunity to select surface charge modifiers for a membrane surface using ester plasticizers containing oppositely charged impurities.

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Potential changes during in situ formation of carriers for cationic surfactant ion-selective electrodes by conditioning

Cited by 7 publications

References 18 publications

Nanomolar Detection of Alkyl Dimethyl Hydroxyethyl Ammonium Surfactant by a Lipophile-doped Solid Contact Electrode

Nanomolar Detection of Alkyl Dimethyl Hydroxyethyl Ammonium Surfactant by a Lipophile-doped Solid Contact Electrode

A PVC‐Membrane Cationic Surfactant Sensitive Potentiometric Sensor: Potentiometric Determination of Dodecyltrimethyl Ammonium Ion

Quantification of Pharmaceutical Bitterness Using a Membrane Electrode Based on a Hydrophobic Tetrakis [3,5-Bis (trifluoromethyl) phenyl] Borate

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