According to the interaction between the gelators that composing the network, organogels can be classified as chemical organogels which are formed by covalent bonds, and physical organogels which are held by weaker physical forces such as hydrogen bonding, van der Waals' interaction, or even π-stacking interaction. [7][8][9] In addition to the controlled release of small molecules, it has been reported that organogels demonstrate viscoelasticity, non-birefringence, thermoreversibility, thermostability, optical clarity, chirality effects, and biocompatibility. [10] Also, conventional organogel materials have been vastly investigated for applications in pharmaceutical fields, the food industry, and the cosmetics industry. [10,11] The designability of organogels allows researchers to select gelators and solvents to achieve different purposes. The targeted functionality, design principle, and functioning mechanism of adhesive organogels are different from conventional ones. Usually, macroscopic phase separation into crystalline and liquid layers is prevented in conventional organogel systems owing to the balance between gelator aggregating forces and solubilizing solvent-aggregate interactions. [8] However, it should be noted that formation and long-term preservation of the surface layer, which prevents direct contact between the deposits and the substrate, is essential to design and fabricate high-performance antiadhesion organogel. It would be favorable that a sufficient amount of liquid is stored in the crosslinked network, which can act as a reservoir so that the surface layer is maintained over a long period of time. The diversity of the gelators gives us a wide range of options in designing high-performance, multifunctional, and durable antiadhesion organogels. For example, a large amount of commercial monomers, precursors, oligomers, and curing agents can be selected to prepare chemical organogels; and supramolecules as well as polyelectrolytes with specific structures can be designed to fabricate physical organogels via self-assembly.Here, we focus on the recent progress of antiadhesion organogel materials with functional surface layers on which easy removal of liquid and solid deposits can be achieved. In particular, strategies for designing multifunctional as well as durable antiadhesion organogels are discussed. Also, potential applications of antiadhesion organogels are envisioned.
Preparation of Antiadhesion Organogel MaterialsAccording to the nature of the molecules, the gelators used to prepare organogels can be categorized as polymeric and Various organogel materials with either a liquid or solid surface layer have recently been designed and prepared. These surface materials can substantially reduce the adhesion of foreign deposits such as water, blood, paint, ice, and so on; therefore, they exhibit great potential for the easy removal of foreign deposits. Here, a brief discussion about the mechanism of organogel materials in reducing adhesion is given; then, examples of liquid organogels for fightin...