“…Some researchers have reported that PB could be formed in single ferricyanide solution in acid condition due to ferricyanide ions could dissociate to free ferric ion for its instability [25][26][27]. In our case, the solution of 1.0 mM K 3 Fe(CN) 6 containing 1.0 M NaNO 3 is neutral.…”
Section: Mechanism Of Pb Formationmentioning
confidence: 69%
“…5, the absorption intensity of ferricyanide decreased largely with storage time. Since there is no other new UV-Vis absorption feature observed besides the decrease of the absorption intensity of ferricyanide, the reduction of ferricyanide ion to ferrocyanide ion or other products can be ruled out [27]. So we can deduce ferric ion was produced due to dissociation of ferricyanide from this measurement.…”
“…Some researchers have reported that PB could be formed in single ferricyanide solution in acid condition due to ferricyanide ions could dissociate to free ferric ion for its instability [25][26][27]. In our case, the solution of 1.0 mM K 3 Fe(CN) 6 containing 1.0 M NaNO 3 is neutral.…”
Section: Mechanism Of Pb Formationmentioning
confidence: 69%
“…5, the absorption intensity of ferricyanide decreased largely with storage time. Since there is no other new UV-Vis absorption feature observed besides the decrease of the absorption intensity of ferricyanide, the reduction of ferricyanide ion to ferrocyanide ion or other products can be ruled out [27]. So we can deduce ferric ion was produced due to dissociation of ferricyanide from this measurement.…”
“…Recently, several groups have reported the marvelous electrocatalytic character of inorganic Prussian blue nanopaticles (PBNPs) towards the reduction of H 2 O 2 compared with that of the conventional PB microparticles or polycrystalline film [21][22][23]. Zhang et al developed PB nanoclusters from an acidic solution of ferricyanide by potentiodynamic technique [24]. Vaucher et al synthesized PBNPs and nanocrystal superlattices in reverse microemulsions [25].…”
“…As a simple and controllable method, electrochemical deposition has been reported for the formation of films which tightly attached to the electrode and retain their properties [25,26]. Intensive research has been focused on using such methods to obtain films in the development of biosensors [27][28][29].…”
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