Soils from an orchard sprayed annually (1953)(1954)(1955)(1956)(1957)(1958)(1959)(1960)(1961)(1962)(1963)(1964)(1965)(1966)(1967)(1968)(1969) with technical DDT (77 % pp'DDT and 22 % op'DDT) were analysed for residues from 1964 until 1969. The amount of DDT found after 17 years was 21 %pp'DDT out of 27.1 kg/ha applied, and 7 % of op'DDT out of 7.6 kg/ha. Thevertical distribution of residues(pp'DDT, pp'DDE, pp'TDE and op'DDT) showed a linear relationship between log amount and depth, with approximately 80% in the top 10 cm of soil. At depths from 50 to 210 cm, residue values were too small to be determined (i.e. < 1 ng/g dry wt). The surface distribution in the orchard showed a systematic pattern of circular areas of residues, with maximum values centred at each trunk (7.5 pg/g) and decreasing rapidly to each alley (1.9 pg/g). The levels ofpp'DDT had reached a steady state (3-4 kg/ha) and the half-life time was calculated as 3.0 years. pp'DDE (1.8 kg/ha) was the main metabolite of pp'DDT. Small amounts of pp'TDE were also found. op'DDT was less persistent thanpp'DDT, with a half-life time of 1.5 years.
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