Preparation and adhesive performance of electrical conductive epoxy-acrylate resin containing silver-plated graphene

Dou, Shuo; Qi, Jiayu; Guo, Xianghai; Yu, Chaosheng

doi:10.1080/01694243.2014.904766

Cited by 15 publications

(6 citation statements)

References 31 publications

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“…The obtained TGA thermograms (Figure S7) suggest that the decrease in electrical conductivity of PMS:PEDOT (5) at higher annealing temperature than 165 °C is ascribed from destructive degradation of the polymer structure. Specifically, weight loss comparison of PMS:PEDOT (5), PSPM (6), and PMS (8) proved that PMDOPA degrades first at 180−300 °C range and then PSPM (6) degrades at the 300−450 °C region (Figure S7). Overall, the thermally damaged polymer 5 demonstrated poor electrical conductivity as shown in Figure 2b.…”

Section: Resultsmentioning

confidence: 97%

“…After identifying the electrical and adhesion properties of the PMS:PEDOT ( 5 ), we compared the test result to the previously reported ECAs’ values. ,,− ,− The ECAs used for comparison were metal (Ag, Zn, or Fe)-containing ECAs, carbon material-based ECAs, and ICP-based ECAs. The Ag-, Zn-, Fe-containing, carbon material-based and ICP-based ECAs are represented as gray, magenta, blue, black, and green dots, respectively, with corresponding reference in the graph (Figure a).…”

Section: Resultsmentioning

confidence: 99%

“…Although ICPs provide unique advantages such as lightness, the ICP filler containing ECA is rare in the literature. There are a handful of examples reporting ICP filler containing ECAs that demonstrate a much lower overall performance compared with metal (Ag)-containing ECAs. ,,− …”

Section: Introductionmentioning

confidence: 99%

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Metal-Free Electrically Conductive Bioinspired Adhesive Polymers

et al. 2019

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The traditional electrically conductive adhesives (ECAs) include heterogeneous metallic and/or carbon-based fillers blended with the organic adhesive polymer matrix. However, those heterogeneousblended ECAs have serious challenges with aggregation, weight, synthetic complexity, large filler contents, and price. This work reports a metal-free, high-performance, and electrically conductive fully organic polymer adhesive, poly(N-methacryloyl-3,4-dihydroxyl-L-phenylalanineco-3-sulfopropyl methacrylate):poly(3,4-ethylenedioxythiophene) (PMS:PEDOT), that is excellently dispersible in water, easy-to-use, lightweight, highly flexible, and biocompatible and has a low-process temperature (23 °C). The new ECA, PMS:PEDOT is prepared in two steps. First, a flexible linker containing copolymer, which possesses the bioinspired adhesive moiety catechol and sulfonate, is synthesized by radical polymerization. Second, EDOT is oxidatively polymerized in the presence of the flexible copolymer matrix to prepare the new ECA (PMS:PEDOT). The PMS:PEDOT exhibits high electrical conductivity up to 2.5 S/cm after annealing and glycerol addition. The bulk adhesion test (lap shear strength tests) showed 1.62 MPa which is much higher than various other commercial adhesives such as epoxy, glass bonder, and ethylene vinyl acetate-based hot melt. This newly developed ECA successfully demonstrates an efficient electrical connection on a circuit board and PET film. This work introduces a new class of materials, a fully organic conducting polymer adhesive, which will become essential for fast growing applications including conducting ink, bioelectronics, batteries, photovoltaics, and ultrathin microsized electronic devices.

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Section: Resultsmentioning

confidence: 97%

Section: Resultsmentioning

confidence: 99%

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Metal-Free Electrically Conductive Bioinspired Adhesive Polymers

et al. 2019

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“…Dou used the silver-plated graphene as conductive filler in the epoxy-acrylate resin, with the addition of 25 wt% silver-plated graphene, the electrical conductivity reached to 0.41 S/cm. [18] As shown in Figure 8, the electrical conductivity increases with increasing Ag/CNTs' concentration. At the beginning, there are little Ag/CNTs being added into the adhesives and connecting less with each other, so the electrical conductivity increases slowly.…”

Section: Conductivity Characteristics Of the Acrylate Resin And Ecasmentioning

confidence: 91%

Electrically conductive adhesives based on acrylate resin filled with silver-plated graphite nanosheets and carbon nanotubes

Qiu

2015

Journal of Adhesion Science and Technology

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Using the electroless plating method, the silver particles were successfully coated on the surface of graphite nanosheets (GNs) and carbon nanotubes (CNTs). Energydispersive spectrometer images showed that the content of silver was about 30-55 wt%, which were supported by the X-ray diffraction images and scanning electronmicroscopy images. Taking advantage of the 'Synergistic Effects' occurring between fillers with different morphologies, we were able to obtain silver-plated graphite nanosheets (Ag/GNs) and silver-plated carbon nanotubes (Ag/CNTs) filled polyacrylate-based electrically conductive adhesives (ECAs). Through the study, we found that the overall properties of the ECAs are optimum when the composite filler is at 30 wt% concentration, consisting of 21 wt% Ag/GNs and 9 wt% Ag/CNTs. Photograph of transmission electron microscope showed that the Ag/GNs and Ag/CNTs dispersed within the polymer matrix homogeneously. The conductivity of the ECAs reaches 8.71 S/cm and the shear strength is 0.47 MPa.

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“…They ascribed the reinforcement to the good dispersion of FGNSs and the strong interfacial adhesion between FGNSs and the thiol‐ene matrix. Dou et al . mixed bisacrylate‐terminated EA with conductive Ag‐plated graphene to prepare electrically conductive adhesive.…”

Section: Introductionmentioning

confidence: 99%

Preparation of transparent nanocomposites from UV‐ and thermo‐curable epoxyacrylate and graphene oxide for the application of corrosion protection coatings

Syu

Lin

Yeh

et al. 2019

Polymer International

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In this study, we report UV‐ and thermo‐curable epoxyacrylate/graphene oxide (EA/GO) nanocomposites that present good transparency, excellent pencil hardness and promising improvement in corrosion protection. A dual‐curable EA oligomer with one terminal epoxide and one double bond at the other end was synthesized by reaction of diglycidyl ether of bisphenol‐A and acrylic acid. After mixing EA and GO with the curing agents and reactive diluent followed by UV cure and thermo‐cure, the resulting EA/GO films on a glass slide with GO loading up to 3 phr exhibited over 86% light transmittance. Furthermore, the pencil hardness was enhanced from 3H for EA to 6H for the EA/GO composite at 2 phr GO loading. The corrosion protection of the EA/GO coatings was evaluated by a potentiodynamic polarization technique and electrochemical impedance spectra. The corrosion potential (Ecorr) of the EA/GO‐coated steel increased with increasing GO loading. Meanwhile, Nyquist and Bode plots indicated that the higher the GO content in the EA/GO coating was, the higher was the coating resistance and also the charge transfer resistance after immersion in salt solution. All these results proved that the GO had positive effects on enhancement of the corrosion resistance. The improved corrosion protection by the EA/GO coatings was mainly due to the enhanced hydrophobicity, the deviation of electron transfer and the increased tortuosity of the diffusion path. The improved corrosion protection and hardness together with the useful dual‐curability make the EA/GO nanocomposite a competitive candidate for corrosion protection coatings. © 2019 Society of Chemical Industry

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Preparation and adhesive performance of electrical conductive epoxy-acrylate resin containing silver-plated graphene

Cited by 15 publications

References 31 publications

Metal-Free Electrically Conductive Bioinspired Adhesive Polymers

Metal-Free Electrically Conductive Bioinspired Adhesive Polymers

Electrically conductive adhesives based on acrylate resin filled with silver-plated graphite nanosheets and carbon nanotubes

Preparation of transparent nanocomposites from UV‐ and thermo‐curable epoxyacrylate and graphene oxide for the application of corrosion protection coatings

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