Preparation and coordination chemistry of Ph2PNHNHpy

Preparation and Coordination Chemistry of n‐Allylaminophosphane

“…Microanalysis [6] The crystal structure of 4 ( Figure 1, Table 1). shows that in the solid state the molecule forms hydrogen-bonded dimers.…”

“…(2) 1.658(6) 1.677(5) P(1)-C (11) 1.822 (6) 1.824(6) P(1)-C (17) 1.820 (7) 1.820(6) P(1)-Pt(1)-P (2) 96.82 (6) 96.14(6) Cl(2)-Pt(1)-Cl (1) 85.09 (6) 86.45(6) N(2)-P(1)-C (11) 110.6(3)…”

“…[7] Unless otherwise stated, all reactions were carried out under oxygen-free nitrogen using standard Schlenk techniques. Diethyl ether and THF were purified by reflux in the presence of sodium/benzo- [8] [{Pd(µ-Cl)(η 3 -C 3 H 5 )} 2 ], [9] [Cu-(MeCN) 4 ][PF 6 ], [10] [AuCl(tht)] (tht = tetrahydrothiophene), [11] [MCl 2 (cod)] (M = Pt or Pd), [12,13] [{RuCl(µ-Cl)(η 6 -p-MeC 6 H 4 -iPr) 2 }], [14] [{Rh(µ-Cl)(cod)} 2 ], [15] [{MCl(µ-Cl)(η 5 -C 5 Me 5 )} 2 ] (M = Rh or Ir), [16] [{PtCl(µ-Cl)(PMe 2 Ph)} 2 ], [17] [{PtCl(µ-Cl)(PMe 2 -Ph)} 2 ] [18] and [{Pd(µ-Cl)(C 10 H 8 N)} 2 ] [19] were prepared according to literature procedures. Chlorodiphenylphosphane and allylamine were distilled prior to use.…”

Aminophosphines derived from N‐phenylpiperazine and N‐ethylpiperazine: Synthesis, oxidation reactions, and molybdenum complexes

“…Although they posses two potential donor atoms, their coordination compounds involve almost exclusively the metal-phosphorus bond [7]. Many aminophosphine ligands and their complexes have been investigated in a number of catalytic processes [6,[8][9][10][11]. Some aminophosphines and derivatives N N R …”

Asymmetric transfer hydrogenation of aromatic ketones with the ruthenium(II) catalyst derived from C2 symmetric N,N′-bis[(1S)-1-benzyl-2-O-(diphenylphosphinite)ethyl]ethanediamide

“…The 31 P-{H} NMR spectra of 1a, 1b and 1c display one singlet at 33.8, 84.9 and 88.7 ppm ( 1 J (PSe) = 805 Hz for 1c) [34,37,38], respectively. The oxidation reaction using aqueous hydrogen peroxide was very rapid and takes place spontaneously under ambient conditions.…”