2016
DOI: 10.1166/jnn.2016.11335
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Preparation and Photoelectrochemical Properties of CdS Nanoparticles Using Supercritical Carbon Dioxide

Abstract: Cadmium sulfide nanoparticles (CdS NPs) that have gas-like diffusivity, low viscosity, and near-zero surface tension were synthesized using supercritical CO 2 (SC CO 2 . The resulting CdS NPs were characterized via field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, and photoluminescence spectroscopy. This paper reports the effects of experimental conditions (e.g., cadmium source and sulfide source) on the morph… Show more

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Cited by 4 publications
(3 citation statements)
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“…Since the first demonstrated single crystal TiO 2 for water splitting to H 2 published in 1972 by Fujishima and Honda [3], photocatalysis has attracted enormous attention of many researchers in various fields including chemistry, physics, materials, and environmental protection. In the past few decades, scientists have made considerable efforts to develop new semiconductor photocatalysts [4,5]; many inexpensive, efficient, and stable photocatalysts have been prepared and used in photochemical sewerage treatments, such as metal oxides (TiO 2 [6], ZnO [7,8]), sulfides [9], and oxynitrides [10]. ZnO is a kind of n-type semiconductor photocatalyst with a wide band gap, high electron excitation binding energy (about 60 meV at room temperature), favorable electric and photonic properties, and oxidation resistance.…”
Section: Introductionmentioning
confidence: 99%
“…Since the first demonstrated single crystal TiO 2 for water splitting to H 2 published in 1972 by Fujishima and Honda [3], photocatalysis has attracted enormous attention of many researchers in various fields including chemistry, physics, materials, and environmental protection. In the past few decades, scientists have made considerable efforts to develop new semiconductor photocatalysts [4,5]; many inexpensive, efficient, and stable photocatalysts have been prepared and used in photochemical sewerage treatments, such as metal oxides (TiO 2 [6], ZnO [7,8]), sulfides [9], and oxynitrides [10]. ZnO is a kind of n-type semiconductor photocatalyst with a wide band gap, high electron excitation binding energy (about 60 meV at room temperature), favorable electric and photonic properties, and oxidation resistance.…”
Section: Introductionmentioning
confidence: 99%
“…Chien-I Wua and Jiann-Wen Huangand [ 39 ] successfully prepared nano-titanium dioxide powder by the supercritical fluid microemulsion system and supercritical drying method with titanium dioxide precursor titanium isopropoxide (TTIP) as raw material. Shancheng Yan et al [ 40 ] successfully synthesized CdS semiconductor nanomaterials in supercritical carbon dioxide medium. The material had a uniform particle size distribution; its particle size ranged from 5 to 10 nm; and it exhibited good gas diffusion, a low viscosity, and a high-quality permeability.…”
Section: Hot Issues and Future Trendsmentioning
confidence: 99%
“…Photochemical sewerage treatments have been organized using photocatalyst such as metal oxides (TiO 2 [10], ZnO [11,12]), sulfides [13], and oxynitrides [14] because of its inexpensive, well organized and their stability. ZnO has been used widely in environmental treatments has it can be used in broad temperature range [15][16][17][18].…”
Section: Introductionmentioning
confidence: 99%