Preparation and properties of Bi2S3 films

Семенов, В. Н.; Ostapenko, Oleksii

doi:10.1007/bf02757922

Cited by 5 publications

(2 citation statements)

References 1 publication

Supporting

Mentioning

Contrasting

Order By: Relevance

“…1,2 Platinum complexes based on thiourea derivatives have great application value in the fields of cancer treatment. 3,4 Also, thioureabased organometallic compounds are employed as precursors in preparing metal sulphide thin films 5,6 which have wide applications in optoelectronic devices, such as window layers for solar cells. 7 In the area of analytical chemistry, thiourea organometallic derivatives have been adopted to develop different anion-selective electrodes.…”

Section: Introductionmentioning

confidence: 99%

Two new bismuth thiourea bromides: crystal structure, growth, and characterization

Li¹,

Li²

2014

Dalton Trans.

View full text Add to dashboard Cite

Crystals of two new bismuth thiourea bromides, bismuth trithiourea bromide (Bi[CS(NH2)2]3Br3, BTB) and bismuth protonated-hexathiourea bromide (Bi[CS(NH2)2H]6Br9, BHB), have been successfully grown from hydrobromic acid solution with different pH values by slow evaporation. Single crystal X-ray diffraction reveals that BTB is isostructural to its Cl-analog crystallizing in a monoclinic space group Cc with unit cell dimensions of a = 8.6238(7) Å, b = 12.2506(11) Å, c = 15.5040(13) Å, β = 90.7810(10)° and Z = 4. In contrast, BHB crystallizes in a trigonal space group R3[combining macron]c with unit cell dimensions of a = b = 12.748(17) Å, c = 40.45(11) Å, and Z = 6. The protonation of the thiourea in BHB is confirmed by the structure solution, IR and Raman spectroscopy. The UV diffuse reflection spectra clearly indicate that both of the two crystals have good optical transparency in the range below 2000 nm. Both compounds decompose above 190 °C, and BHB melts at around 140 °C while BTB possesses a phase transition at 145 °C as indicated by thermogravimetric (TG) and differential thermal analysis (DTA).

show abstract

Section: Introductionmentioning

confidence: 99%

Two new bismuth thiourea bromides: crystal structure, growth, and characterization

Li¹,

Li²

2014

Dalton Trans.

View full text Add to dashboard Cite

show abstract

“…1 Such thiourea-based metal complexes have also been employed as precursors in preparing metal sulfide materials. 2 For example, bismuth sulfide obtained from thiourea complexes is known to be as an important semiconductor. 3 The formation of thiourea complexes of bismuth is used for the qualitative analysis of bismuth in undergraduate inorganic-chemistry courses.…”

mentioning

confidence: 99%

Crystal Structure of S<sub>8</sub> Molecule from Thiourea

Mikuriya

Taniguchi

Koyama

et al. 2020

X-ray Structure Analysis Online

View full text Add to dashboard Cite

Sulfur S8 was isolated from a reaction solution of thiourea and bismuth nitrate in N,N-dimethylformamide. The crystal structure was determined by the single-crystal X-ray diffraction method at 90 K. It crystallizes in the orthorhombic space group Fddd with a = 10.3310(8)Å, b = 12.6786(10)Å, c = 24.3519(19)Å, V = 3189.7(4)Å 3 , Dx = 2.136 g/cm 3 , and Z = 6. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0220 and 0.0570, respectively, for all 1864 independent reflections. The S8 molecule has a crown-shaped ring structure with the α-form.

show abstract

The influences of surfactant concentration on the quality of chalcostibite nanorods

Liu

Tang

et al. 2003

Journal of Crystal Growth

View full text Add to dashboard Cite

Preparation and properties of Bi2S3 films

Cited by 5 publications

References 1 publication

Two new bismuth thiourea bromides: crystal structure, growth, and characterization

Two new bismuth thiourea bromides: crystal structure, growth, and characterization

Crystal Structure of S<sub>8</sub> Molecule from Thiourea

The influences of surfactant concentration on the quality of chalcostibite nanorods

Contact Info

Product

Resources

About