Preparation and properties of lanthanide complexes of some β-diketones

Ismail, M.; Lyle, Samuel J.; Newbery, J. E.

doi:10.1016/0022-1902(69)80387-8

Cited by 27 publications

(7 citation statements)

References 12 publications

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“…Reported methods were used to prepare the ␤-diketonate precursor complex Eu(BTA) 3 (H 2 O) 2 [9] and ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate [10]. Elemental analysis, 1 H and 13 C NMR data for this organic ligand were found to be in good agreement with the reported data [10].…”

Section: Methodssupporting

confidence: 59%

Spectroscopic studies of an europium(III) tris-β-diketonate complex bearing a pyrazolylpyridine ligand

Santos

Coelho

Paz

et al. 2008

Journal of Alloys and Compounds

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Section: Methodssupporting

confidence: 59%

Spectroscopic studies of an europium(III) tris-β-diketonate complex bearing a pyrazolylpyridine ligand

Santos

Coelho

Paz

et al. 2008

Journal of Alloys and Compounds

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“…Dibenzoylmethanate complexes [R(dbm) 3 ]•H 2 O tend to decompose by hydrolysis on heating, and give a basic product, e.g. [R(dbm) 2 (OH)] (Ismail et al, 1969). Further studies have shown that the [R(dbm) 2 (OH)] compounds are polymeric.…”

Section: Synthetic Strategiesmentioning

confidence: 99%

Rare-earth beta-diketonates

Binnemans

2005

Handbook on the Physics and Chemistry of Rare Earths

403

303

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Contents 157 5.6. Solution structure 157 5.7. Electrochemical properties 158 5.8. Thermodynamic properties 159 5.9. Magnetic properties 159 5.10. Crystal-field splittings 160 5.11. Infrared spectra 161 5.12. Chirality sensing 161 5.13. Properties of hemicyanine dyes with βdiketonate counter ions 162 6. Luminescence of β-diketonate complexes 162 6.1. Photoluminescence 162 6.2. Electroluminescence 178 6.3. Triboluminescence 179 6.4. Sensitized chemiluminescence 183 7. From complexes to materials 185 7.1. Sol-gel glasses 185 7.2. Ormosils 186 7.3. β-Diketonates in polymer matrices 190 7.4. β-Diketonates in zeolites 195 7.5. Langmuir-Blodgett films (LB films) 197 7.6. Liquid crystals 200 7.7. Nonlinear optical materials 203 8. From materials to devices 205 8.1. Chelates for lasers 205 8.2. Organic light-emitting diodes (OLEDs) 206 8.3. Liquid crystal displays (LCDs) 216 8.4. Polymeric optical waveguides and amplifiers 217 9. NMR shift reagents 218 9.1. Historical development and general principles 218 9.2. Achiral shift reagents 221 9.3. Chiral shift reagents 226 10. Analytical applications 227 10.1. Trace analysis of lanthanide ions 227 10.2. Trace analysis of organic and biomolecular compounds 229 10.3. Luminescent visualization of latent fingerprints 230 10.4. Chemical sensors 232 10.5. Stationary phases in gas chromatography 232 11. Applications of volatile complexes 233 11.1. Volatile β-diketonate complexes 233 11.2. Gas chromatographic separation of the rare earths 237 11.3. Preparation of thin films by metalorganic chemical vapor deposition (MOCVD) 238 11.4. Preparation of thin films by atomic layer deposition (ALD) 241 11.5. Fuel additives 242 12. Solvent extraction 243 13. Catalytic properties 247

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“…The complex Eu(BTA) 3 Á 2H 2 O (1) was prepared as in the literature [14]. TRIMEB was purchased from Cyclolab and used as received.…”

Section: Methodsmentioning

confidence: 99%

Luminescence properties of the TRIMEB inclusion compound of a europium tris-β-diketonate

Braga

Coelho

Gonçalves

et al. 2008

Journal of Non-Crystalline Solids

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Preparation and properties of lanthanide complexes of some β-diketones

Cited by 27 publications

References 12 publications

Spectroscopic studies of an europium(III) tris-β-diketonate complex bearing a pyrazolylpyridine ligand

Spectroscopic studies of an europium(III) tris-β-diketonate complex bearing a pyrazolylpyridine ligand

Rare-earth beta-diketonates

Luminescence properties of the TRIMEB inclusion compound of a europium tris-β-diketonate

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