Preparation and properties of networks containing chloroprene

Ashworth, J.; Bamford, C. H.; Smith, Edward G.

doi:10.1016/0032-3861(72)90135-8

Cited by 7 publications

(1 citation statement)

References 7 publications

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“…The Mn 2 (CO) 10 ‐mediated photoinitiating system may also be used in the synthesis of a polymer network if combination of macroradicals is the predominant termination route (Scheme ). Network formation versus grafting of the precursor polymers using poly(vinyl trichloroacetate), PMMA, PSt, polyvinyl bromacetate and polychloroprene has been intensively studied using poly(vinyl trichloroacetate) . The termination mechanisms of the polymeric radicals could determine the crosslinking density of the resulting network.…”

Section: Synthetic Applicationsmentioning

confidence: 99%

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Çiftçi

Taşdelen

Yaǧcı

2016

Polymer International

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The environmentally friendly Mn 2 (CO) 10 -based visible light photoinitiating system is a powerful method for the preparation of linear and crosslinked polymeric structures. From a practical point of view, the most important feature of this initiating system is its optical characteristics in the visible range with high quantum yield and good solubility properties. This photoinitiating system is applicable for a variety of monomers that can be polymerized via either radical or cationic mechanisms. Various complex macromolecular structures such as telechelic polymers, block and graft copolymers, polymer networks and surface modifications can be simply prepared by using halogenated precursors. This photoinitiating system is also combined with controlled radical polymerization techniques providing a mild and efficient method for polymer synthesis.

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Section: Synthetic Applicationsmentioning

confidence: 99%

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Çiftçi

Taşdelen

Yaǧcı

2016

Polymer International

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Photoinitiation of Acrylate Polymerization with (Arene)chromium Complexes

Kündig

Kondratenko

et al. 2007

Eur J Inorg Chem

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Photoinitiation of acrylate polymerization by [Cr(êta6-arene)(CO)3] complexes in the presence of an organic chloro compound was investigated. For the bimolecular system, a good correlation between activity and metal-arene and metal-carbonyl bond strength was observed. The highest efficiency was found for an initiator in which the organic chloro compound was tethered to the complexed arene: [Cr(êta6-C6H5CH2OCOCCl3)(CO)3]. The initial steps of the photoinitiation were probed and provided evidence for metal-arene bond cleavage in an Cr(êta2-acrylate)(êta6-arene)(CO)2 complex

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Synthesis, Morphology and Properties of AB Crosslinked Copolymers

Bamford

Eastmond

1974

Recent Advances in Polymer Blends, Grafts, and Blocks

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Preparation and properties of networks containing chloroprene

Cited by 7 publications

References 7 publications

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Photoinitiation of Acrylate Polymerization with (Arene)chromium Complexes

Synthesis, Morphology and Properties of AB Crosslinked Copolymers

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Preparation and properties of networks containing chloroprene

Cited by 7 publications

References 7 publications

Macromolecular design and application using Mn2(CO)10‐based visible light photoinitiating systems

Macromolecular design and application using Mn2(CO)10‐based visible light photoinitiating systems

Photoinitiation of Acrylate Polymerization with (Arene)chromium Complexes

Synthesis, Morphology and Properties of AB Crosslinked Copolymers

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Product

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About

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems

Macromolecular design and application using Mn₂(CO)₁₀‐based visible light photoinitiating systems