Preparation of aminofunctionalized TiO2 surfaces by binding of organophosphates

Preparation of Oleyl Phosphate‐Modified TiO2/Poly(methyl methacrylate) Hybrid Thin Films for Investigation of Their Optical Properties

“…Among phosphorus coupling reagents, phosphoric acid esters are attractive, since they can be easily prepared from commercially available phosphoric acids and alcohols [16]. Another advantage is the flexibility of their structures, leading to facile introduction of desirable functional groups, which play an important role in their compatibility with both polymer matrices and solvents [17][18][19][20][21].…”

Synthesis and characterization of a novel magnetic nano‐palladium Schiff base complex: application in cross‐coupling reactions

“…2‐Aminoethyl dihydrogen phosphate, aminoethyl phosphate or phosphorylethanolamine (with two p K a values of 5.61 and 10.39) is an ethanolamine derivative that is used to build up sphingomyelins (sphingomyelin is a type of sphingolipid that can be found in animal cell membranes, particularly in the membranous myelin sheath that surrounds some nerve cell axons). Also, it has been reported that synthetic phosphorylethanolamine can act as a treatment for Ehrlich ascites tumour cells in cancer therapy . Very recently, Zarghani and Akhlaghinia reported Cu(II) immobilized on aminated ferrite nanoparticles using 2‐aminoethyl dihydrogen phosphate (Fe 3 O 4 @AEPH 2 ‐Cu II ) for conversion of aldoximes to nitriles .…”

Sulfonated nanohydroxyapatite functionalized with 2-aminoethyl dihydrogen phosphate (HAP@AEPH2-SO3H) as a new recyclable and eco-friendly catalyst for rapid one-pot synthesis of 4,4′-(aryl methylene)bis(3-methyl-1H-pyrazol-5-ol)s

“…AEPH 2 is a bifunctional organic molecule that has both a phosphate group and an amino group. 49 Therefore, the phosphate group can be used for binding to the nanoHAP surface and the amino group can also work as an anchoring point for the bonding of several metal ions, and other functional groups. In continuing our efforts toward the development of efficient and environmentally benign heterogeneous catalysts, 50 herein, we designed nano-HAP that is modied with AEPH 2 as a ligand and then sulfonated with chlorosulfonic acid (HAP@AEPH 2 -SO 3 H) (Scheme 1).…”

“…44 Because of usefulness of one-pot reactions for the synthesis of complex molecules such as drug-like molecules, these kind of reactions play an important role in combinatorial chemistry and industrial chemistry. 49 Therefore, the phosphate group can be used for binding to nanoHAP surface and the amino group can also work as an anchoring point for bonding of several metal ions, and other functional groups. On the other hand, heterogeneous catalysts which has been known for many years has become strategically vital for efficient and ecofriendly organic transformations.…”