Preparation of Cu (II) imprinted polymer electrode and its application for potentiometric and voltammetric determination of Cu (II)

Mazloum-Ardakani, Mohammad; Amini, Mohammad K.; Dehghan, Mahdieh; Kordi, Elham; Sheikh-Mohseni, Mohammad Ali

doi:10.1007/s13738-013-0295-4

Cited by 14 publications

(7 citation statements)

References 26 publications

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“…been investigated by several analytical techniques such as atomic absorption spectroscopy, coupled plasma-mass spectrometry, UV spectrophotometry, fluorescence and electrochemical techniques [6][7][8][9][10][11][12]. Analyzes using the electrochemical techniques present advantages when compared to others analytical techniques.…”

Section: Articlementioning

confidence: 99%

Electrode modified with 1,3-bis (4-butyl-1H-1,2,3-triazol-1-yl)propan-2-ol for electrochemical determination of Cu(II) ions in cabbage cultivated with Bordeaux syrup

Sussuchi¹,

Silva²,

Lima³

et al. 2019

Br J Anal Chem

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The modified electrode with 1,3-bis(4-butyl-1H-1,2,3triazol-1-yl)propan-2-ol ligand (CPE/BT) was applied to determinate Cu(II) ions in cabbage cultivated with the use of Bordeaux syrup. The parameters optimization resulted in better analytical signals in B-R buffer solution at pH 5.00, potential of-0.4 V for 900 s on preconcentration, scan rate of 10 mV s-1 and amount of modifier of 5%. Under the electroanalytical method obtained linear behavior in the range of 1.00 x 10-8 to 1.30 x 10-7 mol L-1 , with a correlation coefficient of 0.994. The limit of detection (LOD) and the limit of quantification (LOQ) for determination of copper were with 1.67 x 10-9 mol L-1 and 5.05 x 10-9 mol L-1 , respectively. The electrode was successfully applied in the determination of Cu 2+ on cabbage ("couve") cultivated with Bordeaux syrup and the quantity of copper found was 8.05 µg kg-1 , which is within the standards stipulated by ANVISA.

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Section: Articlementioning

confidence: 99%

Electrode modified with 1,3-bis (4-butyl-1H-1,2,3-triazol-1-yl)propan-2-ol for electrochemical determination of Cu(II) ions in cabbage cultivated with Bordeaux syrup

Sussuchi¹,

Silva²,

Lima³

et al. 2019

Br J Anal Chem

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“…A very similar work has been performed for Cu 2+ by the same authors (Zanganeh and Amini, 2008 ). Also Mazloum-Ardakani et al ( 2013 ) apply the same approach but the dopant of polypyrrole was methyl red. They cite Zanganeh and Amini's work but apparently overlooking the fact that it contains the same imprinting method.…”

Section: Biomimetic Sensors Based On Electrosynthesized Mipsmentioning

confidence: 99%

From Electrochemical Biosensors to Biomimetic Sensors Based on Molecularly Imprinted Polymers in Environmental Determination of Heavy Metals

2017

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Recent work relevant to heavy metal determination by inhibition-enzyme electrochemical biosensors and by selected biomimetic sensors based on molecularly imprinted polymers has been reviewed. General features and peculiar aspects have been evidenced. The replace of biological component by artificial receptors promises higher selectivity and stability, while biosensors keep their capability of producing an integrated response directly related to biological toxicity of the samples.

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“…Until now, great efforts have been devoted to the development of techniques for the determination of copper (II) in water, such as atomic absorption spectrometry (AAS) [20,21], inductively coupled plasma-mass spectroscopy (ICP-MS) [22,23], inductively coupled plasma optical emission spectrometry (ICP-OES) [24,25], anodic cathodic stripping voltammetry (ACSV) [26], electrochemical [27] etc. However, there are disadvantages of these measuring methods such as being time-consuming, having complicated procedures and expensive instruments.…”

Section: Introductionmentioning

confidence: 99%

Citric Acid Capped CdS Quantum Dots for Fluorescence Detection of Copper Ions (II) in Aqueous Solution

et al. 2018

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Citric acid capped CdS quantum dots (CA-CdS QDs), a new assembled fluorescent probe for copper ions (Cu2+), was synthesized successfully by a simple hydrothermal method. In this work, the fluorescence sensor for the detection of heavy and transition metal (HTM) ions has been extensively studied in aqueous solution. The results of the present study indicate that the obtained CA-CdS QDs could detect Cu2+ with high sensitivity and selectivity. It found that the existence of Cu2+ has a significant fluorescence quenching with a large red shifted (from greenish-yellow to yellowish-orange), but not in the presence of 17 other HTM ions. As a result, Cu2S, the energy level below the CdS conduction band, could be formed at the surface of the CA-CdS QDs and leads to the quenching of fluorescence of CA-CdS QDs. Under optimal conditions, the copper ions detection range using the synthesized fluorescence sensor was 1.0 × 10‒8 M to 5.0 × 10‒5 M and the limit of detection (LOD) is 9.2 × 10‒9 M. Besides, the as-synthesized CA-CdS QDs sensor exhibited good selectivity toward Cu2+ relative to other common metal ions. Thus, the CA-CdS QDs has potential applications for detecting Cu2+ in real water samples.

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Preparation of Cu (II) imprinted polymer electrode and its application for potentiometric and voltammetric determination of Cu (II)

Cited by 14 publications

References 26 publications

Electrode modified with 1,3-bis (4-butyl-1H-1,2,3-triazol-1-yl)propan-2-ol for electrochemical determination of Cu(II) ions in cabbage cultivated with Bordeaux syrup

Electrode modified with 1,3-bis (4-butyl-1H-1,2,3-triazol-1-yl)propan-2-ol for electrochemical determination of Cu(II) ions in cabbage cultivated with Bordeaux syrup

From Electrochemical Biosensors to Biomimetic Sensors Based on Molecularly Imprinted Polymers in Environmental Determination of Heavy Metals

Citric Acid Capped CdS Quantum Dots for Fluorescence Detection of Copper Ions (II) in Aqueous Solution

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