Preparation of Fluorine‐Free and Superhydrophobic SiO₂ Film with High Transmittance

Abstract

Superhydrophobic film has broad application prospect in daily life. Herein, superhydrophobic SiO2 film was prepared with chemical modification reducing the film's surface energy and sol mixing increasing its surface roughness. Tetraethoxysilane (TEOS) was used as precursor, trimethylethoxysilane (TMES) was used as modifier. Both the modified SiO2 film and the mixed SiO2 film were obtained with dip‐coating. With the increase of TMES addition, the characteristic peak intensity of hydrophilic hydroxyl group in Fourier transform infrared spectrum (FTIR) decreased, and that of the hydrophobic methyl group increased; the modified SiO2 film surface was relatively smooth and its root‐mean‐square (RMS) roughness ranged 1.86‐5.41 nm, while that of the mixed SiO2 film increased from 11.20 nm to 42.60 nm; the contact angle of the modified SiO2 film increased from 19.08° to 127.37°, while that of the mixed SiO2 film increased from 129.47° to 158.47°; the average transmittance of the modified SiO2 film first decreased from 94.86 % to 94.14 % and then increased to 94.43 %, while that of the mixed SiO2 film decreased gradually from 96.99 % to 94.84 %. Finally, the fluorine‐free superhydrophobic SiO2 film with the average contact angle of 158.47° and the average transmittance of 94.84 % was obtained.

Super‐liquid‐repellent thin film materials for low temperature latent heat thermal energy storage: A comprehensive review of materials for dip‐coating

“…They degrade into toxic and ecologically persistent molecules, such as perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS). Most literature on environmentally friendly STFs focused on inorganic-organic hybrid 185,219,[232][233][234][235][236][237][238] and organic 239 materials. The employed dip-coating process involved combining different surface texture fabrication strategies 174 and less environmentally damaging chemical materials.…”

Fabrication of Durable Superhydrophobic Surface for Versatile Oil/Water Separation Based on HDTMS Modified PPy/ZnO

“…In particular, the inorganic micro/nanoparticles have been used to create the roughness structure for superhydrobicity preparation, such as TiO 2 [ 16 ], SiO 2 [ 17 ], Fe 3 O 4 [ 18 ], ZnO [ 19 ], and carbon nanotubes [ 20 ]. ZnO nanoparticles have significantly attracted interests due to their low cost, accessibility, and stability in application [ 21 ].…”