2019
DOI: 10.3390/nano9121693
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Preparation of pH Responsive Polystyrene and Polyvinyl Pyridine Nanospheres Stabilized by Mickering Microgel Emulsions

Abstract: New pH-sensitive polystyrene, PS, and poly(4-vinylpyridine), P4-VP, nanospheres were prepared by using surfactant-free method based on soft microgels (Mickering emulsion). The formation of stable Mickering cyclohexane/water emulsions was investigated by using soft microgel particles of poly(acrylamide), PAAm, poly(2-acrylamido-2-methylpropane sulfonic acid), PAMPS, and sodium salt of PAMPS, PAMPS-Na, as stabilizers. The dynamic light scattering (DLS), optical microscopy, and scanning electron microscopy (SEM) … Show more

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Cited by 7 publications
(2 citation statements)
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“…Carboxylic groups such as poly(acrylic acid) (PAAc) and poly(methacrylic acid) (PMAAc), [164] sulfonic acid such as poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS) and poly(4-styrenesulfonic acid) (PSSA), [165] phosphonic acid, [166] and boronic acid [167] are the most frequently used acidic groups to develop pH-responsive acidic polymers. Inspired by microorganisms that use flagella for propulsion, researchers fabricated a polymer network using acrylic acid (AAc) as the pH-responsive element along with an acrylamide (AAm)-based hydrogel.…”
Section: Ionization Of Acidic Groupsmentioning
confidence: 99%
“…Carboxylic groups such as poly(acrylic acid) (PAAc) and poly(methacrylic acid) (PMAAc), [164] sulfonic acid such as poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS) and poly(4-styrenesulfonic acid) (PSSA), [165] phosphonic acid, [166] and boronic acid [167] are the most frequently used acidic groups to develop pH-responsive acidic polymers. Inspired by microorganisms that use flagella for propulsion, researchers fabricated a polymer network using acrylic acid (AAc) as the pH-responsive element along with an acrylamide (AAm)-based hydrogel.…”
Section: Ionization Of Acidic Groupsmentioning
confidence: 99%
“…Chemical-responsive miniature robots have exploited various working mechanisms, and the two most common types are pH-responsive soft actuators and water-based responsive actuators (6,41). The pH-responsive soft actuators will swell or shrink based on the pH level of the environmental fluid (140,(150)(151)(152)154). As many organs or tissues inside the human body naturally have pH variations in their physiological environment, like the vagina, gastrointestinal tract, and blood vessels, the pH-responsive soft actuators have shown potential for many medical applications (6,145).…”
Section: Chemical Actuationmentioning
confidence: 99%