Preparation of Tellurium-Nitrogen containing Moieties in Ionic Chainmolecules, Heterocycles, as well as (CF3Se)2Te, (CF3S)2Se, and (CH3)2Te(X)Y (X = Y = NCO, NSO; X = Cl, Y = NSO)

Dworak, Jürgen; Haas, Alois; Hoppmann, Eike; Olteanu, Alexandra; Merz, Klaus; Schäfers, Mike

doi:10.1002/1521-3749(200112)627:12<2639::aid-zaac2639>3.0.co;2-v

Cited by 6 publications

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Preparation of Acyclic and Heterocyclic Tellurathianitrogen Compounds: Contributions to a Better Understanding of Complex Reaction Pathways

Boese¹,

Haas

Hoppmann

et al. 2002

Z. anorg. allg. Chem.

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Reactions between Cl 3 S 3 N 3 and TeCl 4 provide [S 4 N 3 ϩ ][Te 2 Cl 9 Ϫ ] and [S TSNNN U ϩ ][TeCl 5 Ϫ ], the latter molecule, for the first time in SN-chemistry, contains a five membered ring with three nitrogen atoms linked to each other. The course of this unusual reaction is discussed and both structures are proved by X-ray structure determinations. New routes to the known cages (XTeNSN) 3 N (X ϭ F,Cl) result from the decomposition of X 2 Te(NSN) 2 TeX 2 in tetrahydrofuran. In the presence of MCl 3 (M ϭ Ga,Al,Fe) besides (ClTeNSN) 3 N·2THF also [MCl 2 (THF) 4 ϩ ][TeCl 5 ·THF Ϫ ] could be isolated proving that TeCl 4 is an additional product in this decomposition process. The crystal structures for (ClTeNSN) 3 N·2THF and [Cl 2 Al(THF) 4 ϩ ]-[TeCl 5 ·THF Ϫ ] are determined. The reaction steps for this compliDarstellung von azyklischen und heterozyklischen Tellur-Schwefel-StickstoffVerbindungen: Beiträge zum besseren Verständnis komplexer Reaktionswege Inhaltsübersicht. Umsetzungen von Cl 3 S 3 N 3 mit TeCl 4 führen zu [S 4 N 3 ϩ ][Te 2 Cl 9 Ϫ ] und [S TSNNN U ϩ ][TeCl 5 Ϫ ], wobei mit letzterem Molekül, erstmalig in der SN-Chemie, ein Fünfring mit drei aufeinander folgenden Stickstoffatomen erhalten werden konnte. Ein Vorschlag für den Ablauf dieses ungewöhnlichen Prozesses wird vorgenommen. Die Strukturen beider Produkte werden durch Röntgen-strukturanalysen abgesichert. Neue Wege zur Darstellung der literaturbekannten Käfige (XTeNSN) 3 N (X ϭ F,Cl) ergeben sich aus dem Zerfall von X 2 Te(NSN) 2 TeX 2 in Tetrahydrofuran. In Gegenwart von MCl 3 (M ϭ Ga,Al,Fe) entstehen (ClTeNSN) 3 N·2THF und [MCl 2 (THF) 4 ϩ ][TeCl 5 ·THF Ϫ ]. Letzteres beweist die Abspaltung von TeCl 4 . Für beide Verbindungen sind Röntgenstrukturana-

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Preparation of Acyclic and Heterocyclic Tellurathianitrogen Compounds: Contributions to a Better Understanding of Complex Reaction Pathways

Boese¹,

Haas

Hoppmann

et al. 2002

Z. anorg. allg. Chem.

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Compounds of Selenium and Tellurium with Nitrogen Bonds

Klapötke

Krumm

Moll

2011

Patai's Chemistry of Functional Groups

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In the last three decades the field of the traditionally more exotic selenium nitrogen and tellurium nitrogen compounds has developed considerably. This review presents some of the recent results with a focus on crystal structures. The application of nitrogen NMR spectroscopy will be illustrated as an additional useful tool for the characterization of SeN and TeN materials. This chapter includes newer results on binary, ternary, organoselenium and organotellurium amides, imides, azides and other classes of compounds divided into the different oxidation states of selenium and tellurium. Furthermore, the latest selenium and tellurium nitrogen‐containing carbocycles will be mentioned.

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A Summary of Functional Groups Containing Selenium and Tellurium: A Catalog of the Many Groups that are Known and Some that are Not

Hack

Liebman

2013

Patai's Chemistry of Functional Groups

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In the current chapter we provide a catalog of functional groups containing the chalcogens selenium and tellurium where by functional group we mean the central atom, Se or Te, and its local arrangement of atoms bonded to it by single or multiple bonds (its neighborhood). We will do so by cataloging examples of compounds containing the groups. The atoms that define the local neighborhood are limited here to H, C, N, the chalcogens O, S, Se, Te, and the halogens F, Cl, Br and I. As such we avoid Se‐ and Te‐bonding to metals and metalloids and so we will ignore all salts, and we also ignore all groups with formal charges. However arbitrarily, we did include complexes involving species wherein, with appropriate bond‐shifting, we can draw the compound of interest without any formal charges. We have also avoided mention of free radicals and other species with unpaired electrons. All of the groups were explicitly chosen, and have at least one carbon attached to the selenium or tellurium. For each group we generally give one compound as an example (admittedly our choice of name is often unsystematic), a reference to the primary literature (again chosen unsystematically), and the CAS RN for the example compound (when available). Where there is no example we will generally explicitly say so, occasionally with due annotation as NO CAS RN or “no compounds identified” to encourage their study.

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Preparation of Tellurium-Nitrogen containing Moieties in Ionic Chainmolecules, Heterocycles, as well as (CF3Se)2Te, (CF3S)2Se, and (CH3)2Te(X)Y (X = Y = NCO, NSO; X = Cl, Y = NSO)

Cited by 6 publications

References 0 publications

Preparation of Acyclic and Heterocyclic Tellurathianitrogen Compounds: Contributions to a Better Understanding of Complex Reaction Pathways

Preparation of Acyclic and Heterocyclic Tellurathianitrogen Compounds: Contributions to a Better Understanding of Complex Reaction Pathways

Compounds of Selenium and Tellurium with Nitrogen Bonds

A Summary of Functional Groups Containing Selenium and Tellurium: A Catalog of the Many Groups that are Known and Some that are Not

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