2016
DOI: 10.1039/c5ra24248g
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Preponderant adsorption for chlorpyrifos over atrazine by wheat straw-derived biochar: experimental and theoretical studies

Abstract: In competitive sorption, WS750 prefers to adsorb chlorpyrifos over atrazine since that chlorpyrifos has stronger pi–pi interaction with WS750 (23.68 kcal mol−1) and larger lipophilicity (log P= 4.7) than that (22.70 kcal mol−1, log P= 2.7) of atrazine.

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Cited by 50 publications
(23 citation statements)
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“…17 Biochar can be prepared from a variety of industrial and agricultural organic wastes, such as sewage sludge, animal manure, crop straw, and other plant or animal waste. [18][19][20][21] Due to its low cost, wide range of raw material, superior surface properties and rich functional groups, biochar can be used as a potential sorbent to remove many kinds of heavy metal pollutants like Cd, As, Pb and organic pollutants in water. [22][23][24][25] Our previous study indicated that biochar produced from wheat straw had a good adsorption capacity for Cd(II).…”
Section: Introductionmentioning
confidence: 99%
“…17 Biochar can be prepared from a variety of industrial and agricultural organic wastes, such as sewage sludge, animal manure, crop straw, and other plant or animal waste. [18][19][20][21] Due to its low cost, wide range of raw material, superior surface properties and rich functional groups, biochar can be used as a potential sorbent to remove many kinds of heavy metal pollutants like Cd, As, Pb and organic pollutants in water. [22][23][24][25] Our previous study indicated that biochar produced from wheat straw had a good adsorption capacity for Cd(II).…”
Section: Introductionmentioning
confidence: 99%
“…In particular, with readily availability and low cost of materials, the adsorption effect of activated carbons (ACs) on natural organic compounds, metal ions, and synthetic organic matter is very effective [8,9]. ACs can be easily obtained from different agricultural by-products such as nuts, wheat, straw, soybeans, corn stover, and wood [10,11,12,13]. Therefore, pollutants removal through the adsorption onto ACs is an effective method.…”
Section: Introductionmentioning
confidence: 99%
“…One of the main strategies for removal of pesticides from water is the adsorption on different types of materials [5]. Numerous studies can be found in the literature reporting OPs adsorption on mineral surfaces [6,7], carbon-based materials [8][9][10], and materials from graphene family [11]. Nowadays, application of nanoparticles (NPs) in environmental remediation such as water purification by removal of OPs is significantly progressing because of nanomaterial chemistry advantages with respect to conventional technologies [1,12].…”
Section: Introductionmentioning
confidence: 99%