Abstract:The area of north Evia and eastern central Greece is characterized by strong geomorphological contrast and is built up mainly of consolidated rocks. Unconsolidated young sediments of Pleistocene to Holocene age cover the valley and basin¯ats, forming the most productive aquifers in this area. However, two more types of aquifers can be distinguished within the consolidated rock area. The ®rst one is associated with karsti®ed limestones and the second with strongly tectonized ultrama®c rocks. The schist±chert formation, with intercalations of shales and cherts, seals the ultrama®c masses underneath.Surface and spring waters associated with ultrama®c rocks in north Evia and eastern central Greece were studied. Two types of water can be distinguished: (1) high Mg 2 and SiO 2 , bicarbonate as the dominant anion, pH 7 . 4±9 . 2, temperature 9 . 5±16 . 3 8C, low TDS (total dissolved solutes) (459±1037 mg/l), found both in peridotite and serpentinite areas, classi®ed as Mg±HCO 3 type; (2) high Ca 2 , low Mg 2 and SiO 2 , hydroxyl ion as the major anion, pH 11 . 2, temperature 28 8C, very low TDS (122 mg/l), found in peridotite areas, classi®ed as Ca±OH type. The studied waters are highly supersaturated with respect to quartz, amorphous silica, brucite and most low temperature magnesium silicates (antigorite, sepiolite, talc, etc.). These waters show relatively narrow SiO 2 concentration ranges and a trend parallel to the amorphous silica saturation surface. The silica supersaturated waters have the potential to precipitate silica and consequently could aect the people of the local communities that use it as drinking water, causing health problems (kidney stones).