Topological semimetal, a novel state of quantum matter hosting exotic emergent quantum phenomena dictated by the nontrivial band topology, has emerged as a new frontier in condensed-matter physics. Very recently, the coexistence of triply degenerate points of band crossing and Weyl points near the Fermi level was theoretically predicted and experimentally identified in MoP. Via high-pressure electrical transport measurements, we report here the emergence of pressure-induced superconductivity in MoP with a critical transition temperature T c of ca. 2.5 K at ca. 30 GPa. No structural phase transition is observed up to ca. 60 GPa via synchrotron X-ray diffraction study. Accordingly, the topologically nontrivial band protected by the crystal structure symmetries and superconductivity are expected to coexist at pressures above 30 GPa, consistent with density functional theory calculations. Thus, the pressurized MoP represents a promising candidate of topological superconductor. Our finding is expected to stimulate further exploitation of exotic emergent quantum phenomena in novel unconventional fermion system. npj Quantum Materials (2018) 3:28 ; doi:10.1038/s41535-018-0102-7
INTRODUCTIONThe low-energy, long-wavelength quasiparticle excitation near the Fermi level as counterpart of high-energy relativistic Dirac, Weyl, and Majorana fermion has been successfully demonstrated in topological quantum matter with nontrivial band topology such as topological insulator (TI), topological Dirac semimetal (TDS), topological Weyl semimetal (TWS), and topological superconductor (TSC) over the last decade. [1][2][3][4][5][6][7][8][9][10][11][12][13][14] In stark contrast with the gapped bulk state of both TI and TSC, the defining hallmark of TDS and TWS is the presence of linear crossing points of conduction band and valence band near the Fermi level, where two or four bands are exactly degenerate at certain momentum-energy value in the first Brillouin zone, giving rise to a gapless bulk state. Novel macroscopic quantum phenomena they exhibit such as ultrahigh mobility of charge carriers, extremely large linear magnetoresistance, quantum anomalous Hall effect, and chiral anomaly are not only of fundamental interest but also hold potential applications. The recent breakthrough in predicting and identifying unconventional "new fermion" beyond conventional Dirac and Weyl fermion sparked new research interest in the field of topological semimetal. [15][16][17][18][19][20] Among the symmetries of 230 crystal space groups in condensed-matter physics, the threefold, sixfold, and eightfold degenerate quasiparticle excitation emanating from the multiply degenerate points of band crossing near the Fermi level can be protected in a crystal lattice either by symmorphic rotation combined with mirror symmetries or by non-symmorphic