Carbamide Peroxide, an adduct of Urea and Hydrogen Peroxide, is commonly used in the cosmetic and pharmaceutical industries as a solid source of hydrogen peroxide. However, it exhibits explosive properties and can be easily manufactured from readily available household chemicals, making it a potential emerging threat. We carried out a detailed performance assessment, combining experiments, thermochemical calculations and numerical simulations and highlighted a good level of agreement between experimental data from lab, field and underwater firings. A maximum detonation velocity of 3.65 km/s was recorded for unconfined 25 kg UHP charges at 0.85 g/cm 3 (200 mm charge diameter). We determined in these conditions an infinite diameter detonation velocity of 3.94 km/s. These results are also consistent with previous results obtained at small scale under heavy confinement. Airblast measurements highlighted an average 40 % TNT equivalence for impulse and 55 % for peak overpressure at short distance, which are in good agreement with the 57 % (Power Index) calculated from Explo5, while 50 % for bubble energy (explosive power) and 20 % for shock pressure (brisance) were obtained from underwater experiments. The use of different experimental approaches has proven useful to characterise the performances parameters of a non-ideal explosive for risk assessment purposes.
K E Y W O R D Sdetonation, non ideal explosive, performance, urea hydrogen peroxide
| INTRODUCTIONCarbamide Peroxide or Urea Hydrogen Peroxide (UHP) is commonly used in the dental, cosmetic and pharmaceutical industries as a solid source of hydrogen peroxide. This adduct can also be easily manufactured from readily available household chemicals. Like other oxidisers such as ammonium perchlorate [1] or ammonium nitrate [2], UHP exhibits explosive properties [3,4] and could represent a potential emerging threat. Determining UHP detonation performance parameters is hence important for safety purposes.Because there is a need to predict large-scale explosive behaviour from small-scale experiments [5], our