One of the main problems in the study or industrial application of transesterification processes for vegetable oils is how to measure the methyl ester content. In this work, a quick analytical method was developed for assessing the methyl ester content of purified "fuel grade" transesterification products by applying a simple correlation with viscosity. The correlation was tested on a wide range of samples with various methyl ester contents; the results were in agreement with the values measured by gas-chromatographic analysis. In a defined range of weight fractions the correlation allows for the determination of the methyl ester content of purified transesterification products by a single viscosity measurement. This method is especially suitable for process control purposes as it determines the methyl ester content quickly and simply.JAOCS 72, 1399-1404 (1995).KEY WORDS: Density measurement, diesel oil substitute, esterification, methyl ester density, methyl ester determination,
EXPERIMENTAL PROCEDURESIn order to have samples with various degrees of purity, a number of transesterification reactions were caaa'ied out in the laboratory. The soybean oils used for transesteri;fication reactions were refined, edible-grade oils. Methanol, HPLC-grade (Aldrich, Steinheim, Germany), was used without further purification. These oils exhibited an average saponification number of 192, iodine number of 133, and an acid number of 0.06. Karl Fischer titration before use gave values <0.15% water. Reagent-grade sodium hydroxide was used as a catalyst.In order to determine the FAME and glyceride content of the transesterification products, sample preparation and GLC