Cermet-based
solar absorbers containing nickel (Ni) in a nanochain
(NC) structure embedded in an aluminum oxide (Al
2
O
3
) film demonstrated a high absorptance of more than 90% of
the solar spectrum. In this work, Ni NCs were successfully prepared
by a simple chemical reduction method without the assistance of a
template or magnetic field. The formation of Ni nanoparticles (NPs)
in different configurations was controlled by adjusting the NaOH:NiCl
2
molar ratio. Not only was NaOH used to adjust the solution
pH but it also induced the reduction reaction to be faster and so
resulted in a larger number of Ni nuclei. Together with the intrinsic
magnetic property of Ni, Ni NPs tended to orient in a chain-like manner
to form Ni NCs that remained stable throughout the reaction. Increasing
the NaOH:NiCl
2
molar ratio up to 8 led to a uniform morphology
of Ni NCs. However, at higher molar ratios (above 8), the NCs were
likely to collapse at the end of the reaction, forming near-globular
particles. With its unique structure, metallic Ni NCs were employed
by incorporating them into a ceramic layer of Al
2
O
3
, which can be used as efficient cermet materials. Compared
to a conventional cermet with embedded spherical Ni NPs, a 16.4% increase
in solar absorptance was observed with the Ni NCs due to their enhanced
absorption and scattering in the solar spectrum. Moreover, increasing
the Ni NC content in the Al
2
O
3
layer gradually
enhanced the solar absorptance to 0.91 and so was a good solar absorber.