The electron energy distribution function (EEDF) was determined from the second derivative of the I–V Langmuir probe characteristics and, thereafter, theoretically calculated by solving the plasma kinetic equation, using the black wall (BW) approximation, in the positive column of a neon glow discharge. The pressure has been varied from 0.5 to 4 Torr and the current from 10 to 30 mA.The measured electron temperature, density and electric field strength were used as input data for solving the kinetic equation.Comparisons were made between the EEDFs obtained from experiment, the BW approach, the Maxwellian distribution and the Rutcher solution of the kinetic equation in the elastic energy range. The best conditions for the BW approach are found to be under the discharge conditions: current density jd = 4.45 mA cm−2 and normalized electric field strength E/p = 1.88 V cm−1 Torr−1.