“…10) Owing to the weak bonding of electrons to heavy neutral atoms or molecules among single positive-charged ions and electrons, it is not easy to characterize the negative ions, although there have been various methods to measure them such as optical emission spectroscopy (OES), 11) the laser photodetachment (LPD) method, 2,12,13) the ion acoustic wave (time-of-flight) method (IAW) [15][16][17] and the use of electric probes. 11,14,[17][18][19][20][21][22][23][24][25][26] For conventional methods using electric probes and OES, fully ionized plasma with singly positive-charged ions and a Boltzmann electron with one thermal temperature are assumed. In the LPD method, there is a need to define the cross section of a high-power laser beam, which often ionizes the neutral gas leading to the generation of electrons, which which contaminate the detached electrons purely generated from negative ions.…”