2009
DOI: 10.1103/physrevb.79.233101
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Probing the interface ofFe3O4/GaAsthin films by hard x-ray photoelectron spectroscopy

Abstract: Magnetite ͑Fe 3 O 4 ͒ thin films on GaAs have been studied with hard x-ray photoelectron spectroscopy ͑HAXPES͒ and low-energy electron diffraction. Films prepared under different growth conditions are compared with respect to stoichiometry, oxidation, and chemical nature. Employing the considerably enhanced probing depth of HAXPES as compared to conventional x-ray photoelectron spectroscopy allows us to investigate the chemical state of the film-substrate interfaces. The degree of oxidation and intermixing at … Show more

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Cited by 22 publications
(16 citation statements)
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“…The shoulder was due to the overlap of the main peak with the oxide peak, which chemically shifted to higher binding energies, as reported for oxidized GaAs films 14,20 . As θ increases, the probe depth is reduced and the contribution of the interface is enhanced.…”
Section: Intensity I(e)supporting
confidence: 69%
“…The shoulder was due to the overlap of the main peak with the oxide peak, which chemically shifted to higher binding energies, as reported for oxidized GaAs films 14,20 . As θ increases, the probe depth is reduced and the contribution of the interface is enhanced.…”
Section: Intensity I(e)supporting
confidence: 69%
“…For example, it has been shown that arsenic and gallium oxides exist after the deposition of magnetite onto GaAs. 2 In contrast, the oxidation state of the ZnO substrate does not change upon oxide deposition. The heterostructure has, however, a large lattice mismatch of Ϫ8.6% if one assumes that the O sublattices in both materials have to be aligned across the interface.…”
mentioning
confidence: 99%
“…They also calculated the carrier density as a function of the LaAlO 3 layer thickness. In another investigation, Paul et al [36] used energy dependent HAXPES to evaluate thickness of the interface in a Fe 3 O 4 -GaAs bilayer sample which is a promising material for spintronics applications. Beni et al [37] used a similar approach to estimate layer resolved compositional variation in complex Al-Cr-Fe metallic alloy systems.…”
Section: Depth Profiling From Haxpesmentioning
confidence: 98%