PACS. 71.20.Be -Transition metals and alloys. PACS. 73.43.Nq -Quantum phase transitions. PACS. 75.10.Jm -Quantized spin models.Abstract. -The study of quantum phase transitions [1], which are zero-temperature phase transitions between distinct states of matter, is of current interest in research since it allows for a description of low-temperature properties based on universal relations. Here we show that the crystal green dioptase Cu6Si6O18·6H2O, known to the ancient Roman as the gem of Venus, has a magnetic crystal structure, formed by the Cu(II) ions, which allows for a quantum phase transition between an antiferromagnetically ordered state and a quantum spin liquid.c EDP Sciences