Processible and environmentally stable conducting polymers

Elsenbaumer, Ronald L.; Jen, Alex K.‐Y.; Oboodi, R.

doi:10.1016/0379-6779(86)90020-2

Cited by 576 publications

(163 citation statements)

References 12 publications

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“…[49][50][51][52][53][54] Some monomers, as the trimer thiophene-pyrrole-thiophene, given by electropolymerization oxidized films constituted by short chains that 55,56 by reduction in some organic solvents, give soluble reduced oligomers. 57 The oxidized chains are insoluble and by reduction they solubilize in the electrolyte.…”

Section: Shift Of the Molecular Interaction Forces: Electrodissolutionmentioning

confidence: 99%

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Otero

2013

Polymer Reviews

131

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Electro-generations of conducting polymers are fast processes through a complex mechanism of parallel reactions giving mixed materials. The films are three-dimensional electrochemical reactors: reactive macromolecules, ions, and solvent. The film composition and its related properties reviewed here change by oxidation/reduction along several orders of magnitude under control. One reaction shifts different properties (multifunctionality). In one device several reaction driven tools, actuators and sensor, work simultaneously (full integration

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Section: Shift Of the Molecular Interaction Forces: Electrodissolutionmentioning

confidence: 99%

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Otero

2013

Polymer Reviews

131

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“…15 (a) The synthesis of bromo [1,2- Poly(3-alkylthiophene)s are an important synthetic target because their high charge carrier mobilities and absorption profiles make it a useful material for use in FETs and solar cells. 16,17 Until recently, the synthesis of regioregular, low polydispersity polythiophenes was challenging.…”

Section: Detailed Progress Reportmentioning

confidence: 99%

Ring Walking/Oxidative Addition Reactions for the Controlled Synthesis of Conjugated Polymers

Bazan¹

2012

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“…In order to introduce solubility and easy processing, these polythiophenes are typically equipped with alkyl substituents. This approach has been successfully employed in, for example, the development of substituted polythiophenes [12,13]. Apart from introducing solubility, the alkyl substituents also aid in introducing lamellar, supramolecular order in films of regioregular, head-to-tail coupled poly(3-alkylthiophene)s (HT-P3ATs), which is a requisite for the aforementioned application [14,15].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and properties of two novel regioregular conjugated polythiophenes with side-chain containing different substituted end groups

Wang

Feng

Wang

et al. 2012

Designed Monomers and Polymers

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as an oxidizing agent. In P3BLMT and P3BRMT, substituted piperidine rings are connected with the polythiophene backbone through carbon-carbon double bond. While in the two polythiophenes, the significant difference is the substituent linked to the N-atom of the piperidine effectively. Structures of the monomers and the corresponding soluble polymers were elucidated by 1 H NMR, 13 C NMR, and IR. Average molecular weights have been determined by gel permeation chromatography. Photoluminescence spectra and ultraviolet-visible spectra of the two polythiophenes in both solution and solid states were also investigated, and all peaks were bathochromically shifted when they were measured in the solid state. The results of optical and electrochemical measurements indicate that the carbonyl group on the sidechain has obvious influence on the electrochemical properties of the conjugated polythiophenes. In addition, the polymers were also characterized by cyclic voltammetry and scanning electron microscopy.

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Processible and environmentally stable conducting polymers

Cited by 576 publications

References 12 publications

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Ring Walking/Oxidative Addition Reactions for the Controlled Synthesis of Conjugated Polymers

Synthesis and properties of two novel regioregular conjugated polythiophenes with side-chain containing different substituted end groups

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