For the co-processing of pyrolysis-based biocrudes within
petroleum
refineries, a degree of conditioning/upgrading involving the cracking
of the oligomers and (partial) removal of oxygen could be operationally
beneficial. By inducing a complex set of reactions in biomass-derived
fast pyrolysis vapors, catalytic fast pyrolysis (CFP) ensures significant
changes in oxygen functionalities and alleviates oxygen concentration
in the resulting liquid intermediate (CFP-oil). Due to its reduced
oxygen content and acidity, CFP-oil could be considered suitable for
co-feeding in FCC units and/or for co-hydrotreatment (co-HT) with
gas oils within the existing crude oil processing infrastructure.
On the operational side, however, research concerning CFP of biomass
has shown poor results: deoxygenation of pyrolysis vapors goes along
with a progressive reduction in CFP-oil yield. Apart from any control
over catalyst activity, selectivity, and lifetime, the other critical
issue is in the process design, which is complicated by rapid catalyst
deactivation through coke formation and catalyst poisoning by biomass-originated
minerals. This review analyzes the outcome of research efforts concerning in- and ex situ CFP of biomass based on
carefully selected literature studies reporting the results obtained
from meso- and macrolevel laboratory-scale setups, pilot, process
development units (PDU), and (semi-) commercial process units, wherein
the biomass feedstock and catalyst is fed continuously. Key operational
aspects such as the reactor technology, reactive medium, processing
mode, and optimization of process parameters are addressed. The performances
of continuously operated CFP units were benchmarked through a comparison
of yields and elemental compositions of (by-)products. Despite the
considerable research efforts related to CFP technology development,
the co-processing of CFP-oil is still in its infancy. However, in
close collaboration with refinery professionals, it could be made
a serious candidate for biobased co-feeding. For refinery integration,
quality parameters of CFP-oil, e.g., acidity, stability, and miscibility,
should be considered as crucial as its oxygen content.