2013
DOI: 10.6023/cjoc201306015
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Progress in Fluorescent Chemosensors for Chiral Enantiomer Recognition Based on 2,2’-Naphthol Derivatives

Abstract: Being an axial chiral compound with optical activity, 2,2'-naphthol (BINOL) has become one of the basic units for constructing various chiral fluorescent chemosensors in recent years. According to the literatures, chiral BINOL derivatives chemosensors carry out highly enantioselective, sensitive recognition of amino acid and its derivatives, chiral amino alcohols, and α-hydroxycarboxylic acids. In this progress, BINOL derivatives as enantioselective chemosensors for chiral enantiomers are summarized.

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Cited by 3 publications
(2 citation statements)
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“…In this context, macrocycles and supramolecular oligomers/polymers which operate through supramolecular interactions have been reported . Another frequent structural motif encountered in enantioselective fluorescent sensors is the binaphthol system . Several BINOL-derived compounds have been reported, and in some cases, the dendrimeric shape is used for signal amplification or even a derivative containing terpyridine (BINOL-terpyridine) or bis-BINOL connected by a monoamine can be found …”
Section: Introductionmentioning
confidence: 99%
“…In this context, macrocycles and supramolecular oligomers/polymers which operate through supramolecular interactions have been reported . Another frequent structural motif encountered in enantioselective fluorescent sensors is the binaphthol system . Several BINOL-derived compounds have been reported, and in some cases, the dendrimeric shape is used for signal amplification or even a derivative containing terpyridine (BINOL-terpyridine) or bis-BINOL connected by a monoamine can be found …”
Section: Introductionmentioning
confidence: 99%
“…[4,5] As a result of their simplicity and sensitivity, fluorescence sensors have played a significant role in sensing biologically important species in vitro and in vivo. [6][7][8][9][10][11][12][13] In recent years the development of fluorescence sensors based on boronic acids for recognitions of different saccharides has attracted considerable attention owing to their unique ability to effect in aqueous media. [1,[14][15][16] Phenylboronic acid has been reported to rapidly and reversibly interact with 1,2-diols and 1,3-diols to form cyclic esters in aqueous media, [17,18] which means the saccharides that comprise at least two diols groups can interact with boronic acids groups.…”
Section: Introductionmentioning
confidence: 99%