We argue that relativistic nuclear collisions may provide experimental evidence of α clustering in light nuclei. A light α-clustered nucleus has a large intrinsic deformation. When collided against a heavy nucleus at very high energies, this deformation transforms into the deformation of the fireball in the transverse plane. The subsequent collective evolution of the fireball leads to harmonic flow reflecting the deformation of the initial shape, which can be measured with standard methods of relativistic heavy-ion collisions. We illustrate the feasibility of the idea by modeling the 12 C-208 Pb collisions and point out that very significant quantitative and qualitative differences between the α-clustered and uniform 12 C nucleus occur in such quantities as the triangular flow, its event-by-event fluctuations, or the correlations of the elliptic and triangular flows. The proposal offers a possibility of studying low-energy nuclear structure phenomena with "snapshots" made with relativistic heavyion collisions.PACS numbers: 21.60. Gx, 25.75.Ld In this Letter we show that the nuclear collisions in the ultrarelativistic domain may reveal, via harmonic flow, geometric α clustering structure of light nuclei in their ground state. As a particular example we present a study of in 12 C, where a triangular structure induces a corresponding pattern in the collective flow.The α cluster model was proposed even before the discovery of the neutron by Gamow [1] and rests on the compactness, tight binding B α /4 ∼ 7MeV, and stability of the 4 He nucleus [2-4], which fits into the SU(4) Wigner symmetry of the quartet (p ↑, p ↓, n ↑, n ↓) (see, e.g., [5] for an early review and [6] for a historic account, while many references can be traced from [7][8][9][10]). The remaining weak binding per bonding between the α-particles, V αα /bond ∼ 2MeV, accounts for nuclear binding and makes a molecular picture of light nuclei quite natural. This suggests a vivid geometric view of the self-conjugate A = 4n nuclei classified by point group symmetries [11]. For instance, in 9 Be the two α clusters are separated by as much as ∼2 fm, 12 C exhibits a triangular arrangement of the three α's ∼ 3fm apart, 16 O forms a tetrahedron, etc. The condensation of α clusters was described in [12] for 12 C and 16 O. Clustering of 20 Ne has also recently been described within the density functional theory [13]. Model calculations are verified by comparing to the experimental binding energies, the elastic electromagnetic form factor, and the excitation spectra. Experimental evidence for clustering comes from fragmentation studies, see, e.g., [14].Our basic observation and the following methodology stems from the fact that the intrinsic wave functions of light α-clustered nuclei are deformed [15], exhibiting spa- * Wojciech.Broniowski@ifj.edu.pl † earriola@ugr.es tial correlation between the location of clusters. Imagine we collide a light α-clustered nucleus against a heavy nucleus at extremely high energies, as in relativistic colliders (RHIC, LHC) or fixe...