The impact parameter dependence of the ionization of Gold L-subshells has been measured and compared to theoretical values calculated in the SCA framework by Aashamar et al. [17]. Special attention has been paid to large scattering angle measurements and results are obtained for 0lab=30 ~ 45 ~ 65 ~ 90 ~ 110 ~ 130 ~ 153 ~ and 166 ~ Taking into account the sum of L~, L~, L v, L t lines we conclude firstly that the experimental ionization probability P(b) is in good agreement with the theoretical values. Secondly, comparing experimental and theoretical intensity of (L~+L~) and (L v +L~) X-ray lines, we show that ionization of L n and L m subshells is also fairly well described by the SCA model.