Following
the marine shale gas, the continental shale gas also
presents great exploration potential in China. However, few studies
focused on the high-over-mature stage (HOMS) continental shale gas
in terms of mineral composition, pore structure, and gas-bearing properties,
as well as their comparisons with successfully marine shale gas in
the same mature stage, which restricts its better potential evaluation
and “sweet spots” suggestion. In this paper, the lower
Cretaceous Shahezi Formation in Xujiaweizi fault depression, and the
lower Silurian Longmaxi Formation in Pengshui Area, were selected
as the target areas for the study of continental and marine shale
gas in the HOMS. By means of thin sections, scanning electron microscopy,
nitrogen adsorption, high-pressure mercury injection, and methane
isothermal adsorption, a systematic comparison was carried out to
reveal the differences in reservoir characterizes and gas-bearing
properties, and summarize their controlling factors and “sweet
spots” distribution. The type and distribution of organic matter
(OM) dominate the differences between marine and continental shale
in the HOMS. Compared with Longmaxi marine shale with OM of type I–II1 kerogen, there are fewer biogenic siliceous, lower proportion
of organic pores, and more inorganic pores (including dominant clay
related pores, quartz intergranular pores, and dissolution pores)
in Shahezi continental shale with OM of type III–II2 kerogen, corresponding to larger average pore size and smaller specific
surface area (SSA). Quartz content, porosity, and SSA are mainly controlled
by TOC for marine shale, while those are controlled by deposition
and burial depth for continental shale. Plain marsh shale, adjacent
to a coal seam, is favorable for the development of cemented quartz
grains and the limited conversion of mixed illite/smectite (I/S) to
illite, which can effectively restrain the impact of burial depth
on the proportion of intergranular and dissolution pores, porosity,
and pore size for continental shale. I/S, rather than OM, mainly contributes
to the methane adsorption capacity in continental shale, of which
the adsorbed gas content is obviously lower than that of marine shale.
Due to the higher pressure coefficient (PC), porosity and total gas
content of marine shale still increase with increasing the burial
depth, while those of Shahezi continental shale decrease rapidly due
to the slight increase of PC with depth. Some exploration potential
in organic-rich thick shales should be expected in the Shahezi Formation,
which are developed in plain marsh or delta front with burial depths
in the range of 2600–3600 m.