This work reports the production of silver nanoparticles (AgNPs) by a green method using, for the first time, an extract of artichoke (Cynara scolymus L.), and we explore their electrical properties with the aim of using, for the first time, totally green AgNPs on the preparation of highly conductive inks. The ultraviolet-visible spectroscopy (UV–Vis) studies monitored the surface plasmon resonance phenomenon of green-synthesized silver nanoparticles. Biomolecules of Cynara scolymus L. (CS) extract flower were suggested to be responsible for reducing and capping of AgNPs, by Fourier transformed infrared spectroscopy (FTIR) measurements. Elemental analysis was determined by energy dispersive spectroscopy (EDS). Transmission electron microscopy analysis showed nearly spherical silver nanoparticles surrounded and connected by CS extract material with size varying from 30–80 nm. Scanning electron microscope studies revealed films of AgNPs surrounded by CS extract with nearly spherical and uniformly dispersed silver nanoparticles. The peaks in x-ray diffraction pattern are in good match with that of face-centred-cubic form of metallic silver. The purity and thermal stability of the formed AgNP was detected by differential scanning calorimetry-thermal gravimetric analysis, the melting point at through this analysis was closely related to bulk metallic silver which indicates its purity. Moreover, the electrical resistivity test, the four probe method, confirmed that the green synthesized AgNP using artichoke flower extract had highly electrical conductivity: the resistivity of AgNP films was of c.a. after sintering treatment at for 30 min, which was about three times that of bulk silver . Hence, green synthesis can be a prospective way to develop metallic nanoparticles for the preparation of highly conductive inks with low sintering temperature.