Properties of Silver-deposited Graphite Anodes for Lithium Secondary Batteries

Honbo, Hidetoshi; Takeuchi, Seiji; Momose, Hideto; Nishimura, Kinya; Horiba, Tatsuo; Muranaka, Yasushi; Kozono, Yuzo

doi:10.5796/kogyobutsurikagaku.66.939

Cited by 10 publications

(2 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Due to the limitations of SERS substrates, the usual anode materials for lithium ion batteries, such as carbonaceous materials, oxides, and alloys, do not obviously show surface-enhanced effects. Fortunately, Ag, a common SERS substrate, has a similar electrochemical behavior to other anodes for lithium ion batteries; a Li−Ag alloy and the SEI film are formed during the discharge and charge process. , However, it is still unknown whether the Raman signal of the SEI could be surface-enhanced by the Li−Ag alloy. In this paper, the discharged Ag anodes in Ag/Li cells were investigated by micro-Raman spectroscopy.…”

Section: Introductionmentioning

confidence: 99%

“…Fortunately, Ag, a common SERS substrate, has a similar electrochemical behavior to other anodes for lithium ion batteries; a Li-Ag alloy and the SEI film are formed during the discharge and charge process. 30,31 However, it is still unknown whether the Raman signal of the SEI could be surfaceenhanced by the Li-Ag alloy. In this paper, the discharged Ag anodes in Ag/Li cells were investigated by micro-Raman spectroscopy.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Surface-Enhanced Raman Scattering Study on Passivating Films of Ag Electrodes in Lithium Batteries

Pei

et al. 2000

J. Phys. Chem. B

View full text Add to dashboard Cite

Li/Ag and Li/Al electrochemical cells composed of smooth Ag or Al electrode sheets, respectively, and matched with nonaqueous electrolytes were assembled and discharged. Discharged Ag electrodes were investigated using micro-Raman spectromety. Raman bands attributed to the components of the passivating film on the surface of the discharged Ag electrode, such as Li2CO3 and other species, were observed. No characteristic bands from discharged Al electrodes were present in the Raman spectra. This indicates that the Raman signals for the passivating layer are surface-enhanced by discharged Ag electrodes. The formation of a nanometer-scale rough surface caused by a Li−Ag alloy reaction during the discharging process is an important factor in the enhancement. It was also shown that the passivating films formed in various electrolytes could be distinguished by SERS.

show abstract

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%