“…19,20 Due to these properties, pyrene is a sensitive uorescent probe widely used for the characterization of different micro-heterogeneous systems. [21][22][23][24][25][26][27] In a design of uorescent sensors, an interesting approach is to attach two aromatic uorophores close enough so that the electronic excitation of one ring can cause an enhanced interaction of its neighbour, 28 leading to an excited-state dimer or excimer. 29 In particular, calix [4]arene derivatives bearing two highly p-delocalized planar systems such as pyrenes, display an efficient excimer signal due to the intra-or intermolecular p-p interactions between the two pyrenes, and this excimer emission can be perturbed in presence of guest ions/molecules.…”