The application of flexible wearable pressure sensors
in the fields
of pressure sensing, electronic skin, and human health monitoring
has attracted a lot of attention. Herein, cellulose-nanofiber (CNF)-based
aerogels with conducting polymer poly(3,4-ethylene dioxythiophene)/poly(styrenesulfonate)
(PEDOT:PSS) and glutaraldehyde (GA) as cross-linking agent were designed
and prepared by sol–gel cross-linking and freeze-drying. Without
any special treatment, these aerogels presented good flexibility and
piezoresistive properties. As the analysis of SEM, Raman spectrum,
and XPS, the introduction of GA not only improves the mechanical properties
of aerogel (the compressive strength at 80% strain has increased from
48 to 66 kPa) but also affects the doping state of PEDOT, which improves
the sensitivity of aerogel (from 10.65 to 15.18 kPa–1). In addition, the sensor has been successfully applied to monitor
human movements, including not only large movements (joint movements)
but also small-scale muscle movements (cheek puffing and articulation
recognition). It shows its potential as a widely used green pressure
sensor.