Proton conduction in triethylenediamine- and hexamethylenetetramine-sulfate

Takahashi, Tōru; Tanase, Shigeo; Yamamoto, Osamu; Yamauchi, S.

doi:10.1016/s0022-4596(76)80003-5

Cited by 44 publications

(19 citation statements)

References 12 publications

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“…'!tie mechanism involved in this transition is analogous to those observed in many other crystals containin9 aamonium groups [6,7,14,18 '!tIeir DSC thennograms indicated two peaks at.…”

Section: Similar Behaviour Was Observed By Barteit Et Al [17} In Nhsupporting

confidence: 63%

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Electrical properties and phase transitions in ethylenediammonium dinitrate

Santhakumari

Vallabhan

1991

Solid State Ionics

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“…'!tie mechanism involved in this transition is analogous to those observed in many other crystals containin9 aamonium groups [6,7,14,18 '!tIeir DSC thennograms indicated two peaks at.…”

Section: Similar Behaviour Was Observed By Barteit Et Al [17} In Nhsupporting

confidence: 63%

“…Takahashi et al (7] have studied the ionic conductivity in triethylenediammonium sulphate and established protonic conductivity in them.…”

mentioning

confidence: 99%

Electrical properties and phase transitions in ethylenediammonium dinitrate

Santhakumari

Vallabhan

1991

Solid State Ionics

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“…For stationary diffusion, thus dC/dt = 0 and thus from Eq. (16), dJ/dx = 0 and therefore, J is a constant.…”

Section: Fick's Laws and Diffusion Equationsmentioning

confidence: 99%

“…[12][13][14] Similarly, proton conduction is observed in certain anhydrous salts, solid acid compounds and polymeric materials. [15][16][17][18][19][20] In these polymeric materials, ionic motion in saltpolymer complexes is not due to charges hopping from site to site. Rather it is a continuous motion occurring in the amorphous region of the polymeric material.…”

Section: Introductionmentioning

confidence: 99%

Fundamental Aspects of Ion Transport In Solid Electrolytes

Ratnakumar¹,

Narayanan²

2015

Handbook of Solid State Batteries

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“…In a practical solid-state battery involving protonic reaction, the solid electrolyte must not be only proton conductor but should also possess ion transport number very close to unity. Such solid proton conductors (SPC) facilitate possible use of solid electrode materials, which were unstable in the presence of a liquid electrolyte [1][2][3][4].…”

Section: Introductionmentioning

confidence: 99%

The role of electrolyte in governing the performance of protonic solid state battery

Bansod

Bhoga

Singh

et al. 2007

Ionics

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The solid-state proton conductor, P 2 O 5 .5H 2 O, is found very difficult to handle due to presence of a very high content of moisture and corrosive nature. The addition of Al 2 O 3 and SiO 2 into P 2 O 5 .5H 2 O, forming composite electrolytes, obviates said drawback. The Zn+ZnSO 4 used as an anode to prepare cells with different cathode viz. I 2 , MnO 2 , PbO 2 , and V 6 O 13 characterized under different conditions. Open circuit voltage, discharge current and discharge time, on load voltage, discharge capacity, power density, and energy density are evaluated from discharge properties. Protonically conducting composite 70(P 2 O 5 .5H 2 O)/30 [(92SiO 2 )/08(Al 2 O 3 )] is found to be the optimum combination with the optimized 50Zn/50ZnSO 4 as anode and 40MnO 2 /60 graphite as cathode from secondary battery view point.

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Proton conduction in triethylenediamine- and hexamethylenetetramine-sulfate

Cited by 44 publications

References 12 publications

Electrical properties and phase transitions in ethylenediammonium dinitrate

Electrical properties and phase transitions in ethylenediammonium dinitrate

Fundamental Aspects of Ion Transport In Solid Electrolytes

The role of electrolyte in governing the performance of protonic solid state battery

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