A bottom anode with high reflectivity is one of the most important materials for top‐emitting OLEDs. As an anode electrode, stacked ITO/Al‐Ni alloy‐based films, as opposed to conventional stacked ITO/Ag films, were investigated for the first time. It was found that the direct contact technique of the Al‐Ni alloy‐based film with the ITO film using a film annealing process was applicable for OLEDs, as in the case of LCD interconnections that have already been developed by the authors. It was thus concluded that the Al‐Ni alloy‐based films were suitable materials for the anode electrode of OLEDs. They are a better choice than Ag film, due to their low material cost and ease of production of large‐area sputtering targets for large‐Size OLED‐TVs.