“…Both showed the corresponding most prominent fragment ion at m/z 287, which was generated by the breakage of the glycosidic bond and losing the glucose moiety. Secondary fragments were observed for the first eluting isomer at m/z 269, and 259, which were previously described by Qiao et al (2011), using an IT mass analyzer. Finally, two other isomers were characterized as eriodictyol-O-glucosidegallate (65 and 86), based on their molecular formula (and thus mass weight) and MS/MS spectra, since no information related to their MS fragmentation was found in the literature.…”