In the description of transport phenomena, diffusion represents an important aspect. In certain cases, the diffusion may appear together with convection. In this paper, we study the diffusion equation with the self-similar Ansatz. With an appropriate change of variables, we have found an original new type of solution of the diffusion equation for infinite horizon. We derive novel even solutions of diffusion equation for the boundary conditions presented. For completeness, the odd solutions are also mentioned as well, as part of the previous works. We have found a countable set of even and odd solutions, of which linear combinations also fulfill the diffusion equation. Finally, the diffusion equation with a constant source term is discussed, which also has even and odd solutions.