Recently, it has been shown that the quantum information can be masked by spreading it over nonlocal correlations and hidden from the subsystems. However, most of previous works based on only pure states which greatly limits its application. In this work, we provide the exact geometric structure of the maskable states for qudit mixed states, and experimentally investigate the properties of masking using mixed qubit states in an all optical system. The maskable set is determined to be a disk inscribed in Bloch sphere with infinitesimal thickness, within which we observe that the quantum information in the masked states can be completely transferred into bipartite correlations and faithfully restored. The protocol of masking is further utilized to demonstrate tripartite secret sharing, where all the candidates cooperate together to unlock a secret string. Our experiment provide a clear characterization of qubit masking, and sheds light on its potential application on secure quantum information processing.