Quantum chemical studies on chameleonic ligand and its grid-type copper(I) and zinc(II) complexes

A tetradentate ligand of 2-phenyl-4,6-di(pyridin-2-yl)pyrimidine (L) has been synthesized and its complexes with ZnI 2 and CuI have been obtained by hydrothermal method. single crystal X-ray diffraction analysis indicates that ligand L coordinates with Zn(II) ions to form a simple four-coordinate di-nuclear complex, while the complexation of L with Cu(I) constructs a one-dimensional chain polymer. The existence of I -ion hampers the L to assemble grid-type complexes with Zn(II) and Cu(I). Fluorescence spectra show that the L emits blue fluorescence while its Cu(I) polymer decrease the fluorescence intensity and Zn(II) complex quenches the fluorescence.

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Quantum chemical studies on chameleonic ligand and its grid-type copper(I) and zinc(II) complexes

Cited by 2 publications

References 73 publications

CALCULATOR FOR FINDING COMPOSITION OF (Me₁)_x₁(Me₂)_x₂(C_cH_hN_nO_o)_x₃(NO₃)_x₄(H₂O)_x₅(Cl)_x₆ TYPE COMPLEX FROM ELEMENTAL ANALYSIS DATA

CALCULATOR FOR FINDING COMPOSITION OF (Me₁)_x₁(Me₂)_x₂(C_cH_hN_nO_o)_x₃(NO₃)_x₄(H₂O)_x₅(Cl)_x₆ TYPE COMPLEX FROM ELEMENTAL ANALYSIS DATA

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

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Quantum chemical studies on chameleonic ligand and its grid-type copper(I) and zinc(II) complexes

Cited by 2 publications

References 73 publications

CALCULATOR FOR FINDING COMPOSITION OF (Me1)x1(Me2)x2(CcHhNnOo)x3(NO3)x4(H2O)x5(Cl)x6 TYPE COMPLEX FROM ELEMENTAL ANALYSIS DATA

CALCULATOR FOR FINDING COMPOSITION OF (Me1)x1(Me2)x2(CcHhNnOo)x3(NO3)x4(H2O)x5(Cl)x6 TYPE COMPLEX FROM ELEMENTAL ANALYSIS DATA

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

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CALCULATOR FOR FINDING COMPOSITION OF (Me₁)_x₁(Me₂)_x₂(C_cH_hN_nO_o)_x₃(NO₃)_x₄(H₂O)_x₅(Cl)_x₆ TYPE COMPLEX FROM ELEMENTAL ANALYSIS DATA

CALCULATOR FOR FINDING COMPOSITION OF (Me₁)_x₁(Me₂)_x₂(C_cH_hN_nO_o)_x₃(NO₃)_x₄(H₂O)_x₅(Cl)_x₆ TYPE COMPLEX FROM ELEMENTAL ANALYSIS DATA