“…Colloid semiconductor nanocrystals (or quantum dots, QDs) have been widely applied in various fields such as solar cells, light‐emitting didoes, and biological labeling due to their appealing structure and optical properties including high surface activity, small particle size, easy solution processability, and high photoluminescent quantum yield (PLQY). [ 1–4 ] Impurity atom doping into QDs is an efficient strategy to optimize the photoluminescence properties such as emission peak position and emission intensity by adjusting the electron structure of QDs, which has been essential to the development of semiconductor‐based technologies. [ 5,6 ] For example, great progresses have been made with magnetic substitutional impurities in ZnS and ZnSe QDs, [ 7–9 ] these dopants (i.e., Mn, Cu, and Co) are isovalent with the cations and they were replaced to obtain the transition state properties, but no additional carriers are introduced.…”