In this work we study the recurrence problem for quantum Markov chains, which are quantum versions of classical Markov chains introduced by S. Gudder and described in terms of completely positive maps. A notion of monitored recurrence for quantum Markov chains is examined in association with Schur functions, which codify information on the first return to some given state or subspace. Such objects possess important factorization and decomposition properties which allow us to obtain probabilistic results based solely on those parts of the graph where the dynamics takes place, the so-called splitting rules. These rules also yield an alternative to the folding trick to transform a doubly infinite system into a semi-infinite one which doubles the number of internal degrees of freedom. The generalization of Schur functions -so-called FR-functions-to the general context of closed operators in Banach spaces is the key for the present applications to open quantum systems. An important class of examples included in this setting are the open quantum random walks, as described by S. Attal et al., but we will state results in terms of general completely positive trace preserving maps. We also take the opportunity to discuss basic results on recurrence of finite dimensional iterated quantum channels and quantum versions of Kac's Lemma, in close association with recent results on the subject.walks on graphs, see [32] for a recent survey on the subject. Regarding hitting probabilities and recurrence in the setting of OQWs, see [5,14,26,30].This work provides a detailed study of the consequences of the splitting properties for FR-functions regarding recurrence in quantum Markov chains. Two kinds of FR-function splittings, related to factorizations and decompositions into sums of the underlying operator, yield two types of splitting rules for quantum Markov chains and, thus, for the particular case of classical Markov chains. As a consequence of these splitting rules we will see that, similarly to UQWs, the return probability is also invariant under certain local perturbations.Other novel contributions of this paper deal with generalizations of known results on recurrence in classical Markov chains and UQWs. Different quantum generalizations of Kac's lemma for classical Markov chains are commented in Subsect. 2.1. Besides, Theorem 2.8 constitutes the quantum version of a well known result for classical Markov chains, namely, that finiteness and irreducibility imply the positive recurrence of every state, i.e. every state returns to itself with probability one and in a finite expected return time. A similar result holds for finite-dimensional unitary evolutions, which in addition present the striking particularity of exhibiting integer valued expected times for the return to any state [19]. These results has been generalized to the return to a subspace in [9], while [33] proves that they hold for the return to a state in iterated quantum channels whenever they are unital. We extend this property of unital quantum channels to the r...