For synchronic production of highly
valuable olefin and aniline
in a multifunctional system, an innovative thermal coupling reactor
concept equipped with a palladium-based membrane is proposed where
the dehydrogenation of heavy paraffinic hydrocarbon and nitrobenzene
hydrogenation occur inside endothermic and exothermic compartments
of the reactor. In this novel radial flow multifunctional reactor
(RF-MR), the whole interior area of the radial flow tubular reactor
is partitioned into some distinct compartments to convey hydrogen
from the endothermic to exothermic sides. A comprehensive reaction
arrangement is applied with the intention of obtaining an efficient
reactor model. The model outcomes are validated with the industrial
plant data, and an acceptable agreement is attained. The results reveal
that utilizing the RF-MR in linear alkyl benzene plants eventuated
in the adequate consequences. Furthermore, sensitivity analysis for
the RF-MR reveals that the rate of the hydrogenation process, nitrobenzene
conversion, and also the paraffin conversion raises by increasing
exothermic feed stream temperature, while the selectivity of olefin
decreases. The lower olefin production rate in the dehydrogenation
part is attributed to the higher molar flow rate of the exothermic
side. The superior olefin production rate and nitrobenzene conversion
seem to be the advantages of the increasing number of compartments;
however, increasing the catalyst mass is inevitable.