The recovery of hardness and optical absorbance of LiF crystals irradiated with 640 MeV nickel ions under annealing at 450-810 K is investigated. Recovery of the hardness of irradiated crystals is initiated at temperatures above 530 K, at which a transition from a complex absorption spectrum to a spectrum with only one broad peak at 275 nm is observed. Activation energy of 0.13 eV ± 0.02 eV, which is close to that necessary for migration of H centers, is obtained from the annealing data. -5]. However, so far the nature of radiation defects responsible for hardening (possibly small Li colloids, clusters of molecular fluorine and vacancies) is not clearly identified. A study of thermal stability of these defects and recovery of hardness and optical absorbance by thermal annealing of LiF crystals irradiated with fast nickel ions is reported hereafter.