The optimum conditions
for the removal of uranium-238, thorium-232,
and potassium-40 from wastewater and the discharge of nuclear facilities
using multiwalled carbon nanotubes (CNTs) are described. The adsorption
mechanism is mainly attributed to chemical interactions between the
metal ions and surface functional groups of the CNTs. Batch adsorption
experiments are carried out in order to study the effect of different
parameters such as pH, contact time, initial metal ion concentration,
adsorbent dose, and temperatures. Maximum metal removal (>98%)
from
solutions containing 20–120 Bq/L metal ions is achieved using
a contact time of 15 min, a pH of 6.0, and 10 mg/L CNTs. The effect
of temperature on the kinetics and equilibrium of adsorption on CNT
particles is examined. Consistent with an exothermic reaction, an
increase in the temperature resulted in an increase in the adsorption
rate. Langmuir, Freundlich, and Dubinin–Radushkevich isotherms
are applied to the data obtained at various temperatures. The Langmuir
adsorption model is the best for data interpretations. The kinetics
of adsorption reveals a pseudo-second-order mechanism. Thermodynamic
parameters at 293 K (Δ
G
°, Δ
H
°, and Δ
S
°) for U-238,
Th-232, and K-40 are −14590.7 kJ/mol, −6.66 kJ/mol,
and 26.47 J/(mol K), −96,96.5 kJ/mol, −2.48 kJ/mol,
and 14.17 J/(mol K), and −3922.09 kJ/mol, −1.32 kJ/mol,
and 6.12 J/(mol K), respectively.