Raman and IR-ATR spectroscopy studies of heteroepitaxial structures with a GaN:C top layer

Abstract

Raman spectroscopy, with both resonant and non-resonant excitation, and infra-red (IR) spectroscopy, in the attenuated total reflection (ATR) configuration, was employed to study lattice vibration modes in a set of carbon-doped GaN (GaN:C) epilayers grown by metalorganic vapour phase epitaxy (MOVPE). We analyse Raman and IR-ATR spectra from the point of view of possible effects of the carbon doping, namely: (i) local vibration mode of C atom in a N sublattice (whose frequency we theoretically estimate as 768 cm-1 using an isotope defect model), and (ii) shift in the positions of longitudinal modes owing to the phonon-plasmon coupling. We find only some indirect hints of the doping effect on the resonant Raman spectra. However, we show theoretically and confirm experimentally that the IR-ATR spectroscopy can be a much more sensitive tool for this purpose, at least for the considered structures. A weak perturbation of the dielectric function of GaN:C, caused by the substitutional carbon impurity, is shown to produce a measurable dip in the ATR reflectivity spectra at ≈ 770 cm-1 , for both p-and s-polarizations. Moreover, it influences a specific (guided-wave-type) mode observed at ≈ 737 cm-1 , originating from the GaN layer, which appears in the narrow frequency window where the real parts of the two components of the dielectric tensor of the hexagonal crystal have the opposite signs. This interpretation is supported by our modelling of the whole multilayer structure using a transfer matrix formalism.

An Experimental Study of Carbon-Doped GaN via Solid–Gas Reaction Route and Investigation of Its Defect-Related Luminescence

“…Although, over the years, multiple theoretical and experimental approaches have been used for understanding the nature of these defect states, their respective energy levels, and the related emissions; an experimental characterization of YL is still needed. A study on substrate-free C-doped GaN is of interest for vibrational spectroscopic characterizations as a Reststrahlen-related band exhibition of the substrate obstructs localized vibrational modes (LVMs) of a carbon dopant in GaN. − …”

Tamm Polaritons and Cavity Modes in the FIR Range

“…Therefore, the semiconductor acts as a mirror in this frequency range, similar to a metal but it is less lossy because the imaginary part peaks at and the width of this peak is just few cm -1 for a good crystal, while the width of the reststrahlen band is typically a few tens of cm -1 . As known, multilayer structures containing polar semiconductors support evanescent waves named surface phonon-polaritons, which occur in their reststrahlen band [10,11]. Such polaritons are characterized by an imaginary wavevector component in the direction perpendicular to the surface (to be denoted as z direction), i.e.…”